The 99th Annual Meeting of The Chemical Society of Japan

Date: March 16th - 19th, 2019

Venue: Okamoto Campus, Konan University, Kobe, Japan

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Room I3

Bldg. 10 1013


[Organic Chemistry -Reaction and Synthesis- Aromatic Compounds]


Saturday, March 16, AM

Chair: IIDA, Keisuke (10:00-10:50)

* 9:50-10:00: interval for laptop PC connection.(1I3-07, 1I3-08, 1I3-09, 1I3-10, 1I3-11)

1I3-07
Direct α-Arylation of Alcohols with Aryl Halides through a Radical Chain Mechanism (Sch. Sci. Tech., Kwansei Gakuin Univ.) º AOKI, Kohei; IKEDA, Yuko; UENO, Ryota; SHIRAKAWA, Eiji

1I3-08
Homolytic Aromatic Substitution with Alkyl Radicals Generated through Hydrogen Abstraction and β-Scission (Sch. Sci. Tech., Kwansei Gakuin Univ.) º IKEDA, Yuko; SHIRAKAWA, Eiji

1I3-09
Diversity-oriented Synthesis of Multisubstituted Benzoheteroles through Efficient Transformations of Trifluoromethyl Group (IBB, Tokyo Med. and Dental Univ.) º IKEDA, Mai; MATSUZAWA, Tsubasa; MORITA, Takamoto; YOSHIDA, Suguru; HOSOYA, Takamitsu

1I3-10
Facile Synthesis of N-Arylphenothiazines by Rearrangement of o-Sulfanylanilines (IBB, Tokyo Med. and Dental Univ.) º MATSUZAWA, Tsubasa; YOSHIDA, Suguru; HOSOYA, Takamitsu

1I3-11
Direct Synthesis of Phenoxathiins by the Reaction of Aryl Thiosulfonates Bearing a Hydroxy Group with Arynes (IBB, Tokyo Med. and Dental Univ.) º KANEMOTO, Kazuya; YOSHIDA, Suguru; HOSOYA, Takamitsu


Chair: YOSHIDA, Suguru (11:00-11:50)

* 10:50-11:00: interval for laptop PC connection.(1I3-13, 1I3-14, 1I3-15, 1I3-16, 1I3-17)

1I3-13
Brønsted Acid-Catalyzed One-Step Construction of o-Diindolylbenzenes (Sch. Sci. Eng., Meiji Univ.) º OKUSA, Takumi; TSUCHIMOTO, Teruhisa

1I3-14
Brønsted Acid-Catalyzed Synthesis of Helical Polycyclic Aromatic Hydrocarbons (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º SHOJI, Noriaki; HAYASHI, Masaki; FUJITA, Takeshi; ICHIKAWA, Junji

1I3-15
Asymmetric Mannich-type reaction of malononitrile with α-ketiminoesters using acid-base bifunctional catalyst (Grad. Sch. Sci., Chiba Univ.) º NISHIDA, Yuki; KUWANO, Satoru; ARAI, Takayoshi

1I3-16
Disulfide-catalyzed Aromatic Iodination Reaction (Grad. Sch. Sci., Chiba Univ.) º ISHIDA, Shunsuke; IIDA, Keisuke; WATANABE, Takamichi; ARAI, Takayoshi

1I3-17
Regioselectivity control of aromatic nucleophilic substitution reaction by combination of substituent of polyfluoroarene and nucleophilic agent (Fac. Sci., Gakushuin Univ.) º AMATATSU, Julia; SHIMADA, Naohiro; MIYAGAWA, Masamichi; AKIYAMA, Takahiko


Saturday, March 16, PM

Chair: NISHII, Yuji (13:00-13:50)

* 12:50-13:00: interval for laptop PC connection.(1I3-25, 1I3-27, 1I3-28, 1I3-29)

1I3-25*#
Diboron-Catalyzed Dehydrative Amidation of Aromatic Carboxylic Acids with Amines (Grad. Sch. Sci., Nagoya Univ.) º BAGAL, Dattatraya B.; SAWANT, Dinesh N.; KALIYAMOORTHY, Selvam; SAITO, Susumu

1I3-27
Convergent Synthesis of Polycyclic Compounds via Arynes Bearing a 1,3-Diyne Moiety (IBB, Tokyo Med. and Dental Univ.) º SHIMIZU, Keita; UCHIDA, Keisuke; YOSHIDA, Suguru; HOSOYA, Takamitsu

1I3-28
Facile Synthesis of o-Iodoaryl Triflates by Desilyliodination (IBB, Tokyo Med. and Dental Univ.) º YOSHIDA, Suguru; HAZAMA, Yuki; KANEMOTO, Kazuya; NAKAMURA, Yu; HOSOYA, Takamitsu

1I3-29
Facile Synthesis of Multisubstituted Diarylpyrazoles by Sequential Cross-coupling and Consecutive Aryne Generations (IBB, Tokyo Med. and Dental Univ.) º KOBAYASHI, Tsuneyuki; YOSHIDA, Suguru; HOSOYA, Takamitsu


Chair: TAKENAKA, Kazuhiro (14:00-14:50)

* 13:50-14:00: interval for laptop PC connection.(1I3-31, 1I3-32, 1I3-33, 1I3-34, 1I3-35)

1I3-31
Direct Arylation of Parent Nitronyl Nitroxide by Pd-catalyzed Cross-Coupling Reaction (Grad. Sch. Eng. Sci., Osaka Univ.) º NAKAMURA, Fumiya; SUZUKI, Shuichi; NAOTA, Takeshi

1I3-32
Pd(II)-catalyzed acetalization diazoquinone (Grad. Sch. Eng., KIT) º FUJIMURA, Ryo; NISHIMURA, Tomoaki; TAKAHASHI, Shuhei; SHIMOOKA, Hirokazu; OKAUCHI, Tatsuo; KITAMURA, Mitsuru

1I3-33
Diazotization of phenols with azido imidazolinium salt (Grad. Sch. Eng., KIT) º ETO, Takashi; KONAI, Kazushige; TAKAHASHI, Shuhei; SHIMOOKA, Hirokazu; OKAUCHI, Tatsuo; KITAMURA, Mitsuru

1I3-34
Acid-Mediated Aromatic Carbon-Fluorine Bond Activation: Coupling of Fluorobenzofurans with Arenes (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º MORIOKA, Ryuraro; FUKUDA, Takuya; FUJITA, Takeshi; ICHIKAWA, Junji

1I3-35
Synthetic Route to Trifluoromethyl Indoles via Oxidative Cyclization of Sulfonamido-Substituted Styrenes (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º IDE, Keisuke; MOJIMA, Tomoya; FUJITA, Takeshi; ICHIKAWA, Junji


Chair: FUJITA, Takeshi (15:00-15:50)

* 14:50-15:00: interval for laptop PC connection.(1I3-37, 1I3-38, 1I3-39, 1I3-40, 1I3-41)

1I3-37
Synthesis of boron complex using 1-azaazulene derivatives as a ligand (Fac. Sci. Technol., TUS) º CHISHIMA, Tatsuya; YAMAMOTO, Kazuki; GUNJI, Takahiro

1I3-38
Al-catalyzed Friedel-Crafts-Type Benzylation (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º HACHIYA, Asuka; YURINO, Taiga; OHKUMA, Takeshi

1I3-39
Sulfide-Catalyzed Halogenation of Aromatic Compounds using N-Halosuccinimides (Grad. Sch. Eng., Osaka Univ.) º IKEDA, Mitsuhiro; NISHII, Yuji; MIURA, Masahiro

1I3-40
Construction of trifluoromethylated quaternary stereocenters via p-quinonemethides (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º TERASHIMA, Kyu; SHIBATA, Ryunosuke; KAWASAKI-TAKASUKA, Tomoko; YAMAZAKI, Takashi

1I3-41#
Development of New Chiral Ligands Based on a Tetraphenylene Backbone (ISIR, Osaka Univ.) º KATAOKA, Kousuke; TAKENAKA, Kazuhiro; SASAI, Hiroaki


Chair: YURINO, Taiga (16:00-16:40)

* 15:50-16:00: interval for laptop PC connection.(1I3-43, 1I3-44, 1I3-45, 1I3-46)

1I3-43
Acceleration Effect of a Single Electron Donor in the Electron-Catalyzed Cross-Coupling Reaction (Sch. Sci. Tech., Kwansei Gakuin Univ.) º MIZUSAWA, Sahiro; IKEDA, Yuko; SHIRAKAWA, Eiji

1I3-44
Electron-Catalyzed Cross-Coupling of Arylboron Compounds with Aryl Halides Accelerated by a Photoredox Catalysis (Sch. Sci. Tech., Kwansei Gakuin Univ.) º OTA, Yuki; IKEDA, Yuko; SHIRAKAWA, Eiji

1I3-45
Photo-induced transformation of arylsulfonimides through aryl migration (Grad. Sch. Sci., Nagoya Univ.) º SAKAKIBARA, Yota; MURAKAMI, Kei; ITAMI, Kenichiro

1I3-46
Deprotection of 2-nitrobenzyl ether by using LED lamp. (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º KUROBOSHI, Manabu; KAMIO, Nana


Sunday, March 17, AM

Chair: TAKIKAWA, Hiroshi (09:00-09:50)

* 8:50-9:00: interval for laptop PC connection.(2I3-01, 2I3-02, 2I3-03, 2I3-04, 2I3-05)

2I3-01
Facile Synthesis of Diverse Quinolines Based on “Aryne Relay Chemistry” (IBB, Tokyo Med. and Dental Univ.) º NAKAMURA, Yu; YOSHIDA, Suguru; HOSOYA, Takamitsu

2I3-02
Concise Synthesis of Multisubstituted Aromatic Organosulfurs with Various Valence States Based on Aryne Relay Chemistry (IBB, Tokyo Med. and Dental Univ.) º MIYATA, Yoshihiro; NAKAMURA, Yu; UCHIDA, Keisuke; YOSHIDA, Suguru; HOSOYA, Takamitsu

2I3-03
Generation of Arynes Triggered by Activation of Iodo Group with Hydrosilane and Base (IBB, Tokyo Med. and Dental Univ.) º UCHIDA, Keisuke; YOSHIDA, Suguru; HOSOYA, Takamitsu

2I3-04
Synthesis of dicyclobutabiphenylenes having electron withdrawing groups (Grad. Sch. Sci. Tech., Kwansei Gakuin Univ.) º IKESHIMA, Ryo; HAMURA, Toshiyuki

2I3-05
Synthesis of novel π-conjugated molecules with biphenylene framework (Sch. Sci. Tech., Kwansei Gakuin Univ.) º YAMAGUCHI, Shohei; IKESHIMA, Ryo; HAMURA, Toshiyuki


Chair: HAMURA, Toshiyuki (10:00-10:50)

* 9:50-10:00: interval for laptop PC connection.(2I3-07, 2I3-09, 2I3-11)

2I3-07*#
Synthesis and Physicochemical Properties of Air-Stable Ynamines, and the Subsequent Dephosphorylative Click Reaction (Fac. of Eng., Okayama Univ. of Sci.) º OKUDA, Yasuhiro; SEO, Tomoyo; SHIGEZANE, Yuki; ORITA, Akihiro

2I3-09*#
Intramolecular Benzyne-Phenol [4+2] Cycloaddition Enabled by Silicon-Tether Strategy (Sch. Sci., Tokyo Tech.; Grad. Sch. Pharm. Sci., Kyoto Univ.; Grad. Sch. Pharm., The Univ. of Tokyo; Elements Chem. Lab., RIKEN) º NISHII, Arata; TAKIKAWA, Hiroshi; HIRANO, Keiichi; OHMORI, Ken; UCHIYAMA, Masanobu; SUZUKI, Keisuke

2I3-11
Facile construction via ketol rearrangement reaction of benzobicyclo[3.2.1]octadiene structure (Sch. Sci., Tokyo Tech.; Grad. Sch. Pharm. Sci., Kyoto Univ.) º TANAKA, Masato; NISHII, Arata; TAKIKAWA, Hiroshi; OHMORI, Ken; SUZUKI, Keisuke


Chair: HOSOYA, Takamitsu (11:00-11:50)

* 10:50-11:00: interval for laptop PC connection.(2I3-13, 2I3-15, 2I3-16, 2I3-17)

2I3-13*#
Synthesis of α-Trifluoromethylated Ketones using Trifluoromethanesulfonic Acid or Anhydride (Grad. Sch. Sci. Tech., Yamaguchi Univ.; Grad. Sch. Sci. Tech., Yamaguchi Univ.) º KAWAMOTO, Takuji; SASAKI, Rio; TAKATA, Ryotaro; NOGUCHI, Kohki; MOCHIMIZO, Keisuke; KAMIMURA, Akio

2I3-15
Development of stimuli-responsive chiral auxiliary that switches the stereoselectivity in response to external stimuli (Grad. Sch. Eng., TUS) º JINDE, Akinori; IMAHORI, Tatsushi

2I3-16
Stimuli-responsive phosphoramide Catalysts toward universal control of Diastereoselectivity in Mukaiyama Aldol Reaction (Grad. Sch. Eng., TUS) º SASAKI, Aya; ABE, Yuina; IMAHORI, Tathushi

2I3-17
Reductive coupling reaction behavior of neighbouring carbonyl groups in peri-aroylnaphthalene compound and spatial organization of the substrate. (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º MIZUMA, Risa; MIDO, Takahiro; IITSUKA, Hiroaki; DOI, Taiki; YAKITA, Daisuke; YONEZAWA, Noriyuki; OKAMOTO, Akiko


Sunday, March 17, PM

Chair: KAWAMOTO, Takuji (13:00-13:50)

* 12:50-13:00: interval for laptop PC connection.(2I3-25, 2I3-27, 2I3-28, 2I3-29)

2I3-25*
Sequential Click Reaction Based on Azido-type Selective Protection via Formation of Phosphazide (IBB, Tokyo Med. and Dental Univ.) º MEGURO, Tomohiro; IGAWA, Kzunobu; TOMOOKA, Katsuhiko; YOSHIDA, Suguru; HOSOYA, Takamitsu

2I3-27
Development of Novel Click Reaction Tools for Efficient Synthesis of Multifunctional Molecular Probes (IBB, Tokyo Med. and Dental Univ.) º KORI, Daisuke; NISHIYAMA, Yoshitake; MAKIO, Naoaki; FUJII, Saki; YOSHIDA, Suguru; HOSOYA, Takamitsu

2I3-28#
Oxidative Ring Expansion Reaction for Synthesis of 7-Membered Ring-fused π-Conjugated Polycycles (Grad. Sch. Sci., Tohoku Univ.) º ZHANG, Sheng; JIN, Tienan; TERADA, Masahiro

2I3-29
Synthesis of Novel Polysilylated Anthracene Derivatives via Reductive Silylation and Their Reactions (Grad. Sch. Sci. Tech., Gunma Univ.) º KANNO, Ken-ichiro; KONITA, Shiho; SHINOHARA, Ayano; KYUSHIN, Soichiro


Chair: TERADA, Masahiro (14:00-14:50)

* 13:50-14:00: interval for laptop PC connection.(2I3-31, 2I3-34, 2I3-35)

2I3-31 Young Scholar Lectures of CSJ#
Development of catalytic aromatic functionalization toward new π-aromatics (WPI-ITbM, Nagoya Univ.) º MURAKAMI, Kei

2I3-34#
Synthesis of Sterically Hindered 4,5-Diarylphenanthrenes via Acid-catalyzed Bisannulation of Benzenediacetaldehydes with Alkynes (Grad. Sch. Sci., Nagoya Univ.) º LI, Yuanming; YAGI, Akiko; ITAMI, Kenichiro

2I3-35
The substituent effect of axial rotation behavior of biphenyl bridged anthracene dimer (Grad. Sch. Sci., Osaka Univ.) º YAMANO, Masashi; NISHIUCHI, Tomohiko; KUBO, Takashi


Chair: MURAKAMI, Kei (15:00-15:50)

* 14:50-15:00: interval for laptop PC connection.(2I3-37, 2I3-38, 2I3-39, 2I3-40, 2I3-41)

2I3-37
Synthesis of Isoanthracenofuran Derivatives by Cycloaddition of Didehydroisobenzofuran (Sch. Sci. Tech., Kwansei Gakuin Univ.) º JUNG, Sunna; MIYAKAWA, Kaoru; MATSUOKA, Suguru; HAMURA, Toshiyuki

2I3-38
Synthesis of Disc-Shaped Aromatic Polyketones (Sch. Sci. Tech., Kwansei Gakuin Univ.) º KANZAKI, Masayoshi; ADACHI, Kazuhiko; HAMURA, Toshiyuki

2I3-39
Synthesis of Propeller-Shaped Isobenzofuran and its Application (Sch. Sci. Tech., Kwansei Gakuin Univ.) º NAKAHASHI, Ryota; JUNG, Sunna; HAMURA, Toshiyuki

2I3-40
Synthesis and properties of 2,2'-bi(1,4-dialkyl-9,10-anthraquinone) (Grad. Sch. Eng., The Univ. of Shiga Pref.) º KONDO, Aki; KATO, Shin-ichiro; KITAMURA, Chitoshi

2I3-41
Synthesis and Properties of Dicyclopenta[b,g]naphthalenes Fused with Various Aromatics (Sch. Eng., The Univ. of Shiga Pref.; Sch. Sci. Tech., Gunma Univ.; IMCE, Kyushu Univ.) º HAYASHI, Hideki; MIYAUCHI, Hidenori; MATSUMOTO, Taisuke; NAKAMURA, Yosuke; KIYAMURA, Chitoshi; KATO, Shin-ichiro


Chair: HIROTO, Satoru (16:00-16:50)

* 15:50-16:00: interval for laptop PC connection.(2I3-43, 2I3-45, 2I3-46, 2I3-47)

2I3-43*#
Syntheses of Functionalized Polyaromatic Compounds by Using Quinoidal Reactive Molecules (Sch. Sci. Tech., Kwansei Gakuin Univ.) º KITAMURA, Kei; KUDO, Ryoji; HAMURA, Toshiyuki

2I3-45
Synthesis of substituted tetracenes by using alkynyl isobenzofuran (Sch. Sci. Tech., Kwansei Gakuin Univ.) º SOGA, Eri; KEI, Kitamura; HAMURA, Toshiyuki

2I3-46
Synthesis and stereochemical behavior of 1,10-anthracenephane (Sch. Sci. Tech., Kwansei Gakuin Univ.) º SOGA, Eri; KITAMURA, Kei; IGAWA, Kazunobu; TOMOOKA, Katsuhiko; HAMURA, Toshiyuki

2I3-47
Synthesis of π-conjugated molecules based on thermally-stable ortho-quinodimethane (Sch. Sci. Tech., Kwansei Gakuin Univ.) º ADACHI, Kazuhiko; HAMURA, Toshiyuki


Monday, March 18, AM

Chair: MOROFUJI, Tatsuya (10:00-10:50)

* 9:50-10:00: interval for laptop PC connection.(3I3-07, 3I3-08, 3I3-09, 3I3-10, 3I3-11)

3I3-07
Development of facile synthetic methods of H2O@C60 using a triazine derivative (ICR, Kyoto Univ.) º KIM, Kyusun; ZHANG, Sheng; HASHIKAWA, Yoshifumi; MURATA, Yasujiro

3I3-08#
Fullerene-Cation-Mediated Synthesis of Cyclo[60]fullerenes with 5-Membered-Ring and their Application in Perovskite Solar Cells (Grad. Sch. Eng., The Univ. of Tokyo) º LIN, Hao-sheng; JEON, Il; MARUYAMA, Shigeo; MATSUO, Yutaka

3I3-09
Synthesis of Fully Fused Hexabenzocoronene Dimer (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST) º URYU, Mizuho; MURAKAMI, Kei; ITAMI, Kenichiro

3I3-10
Synthesis of Coronene Analogue by Intramolecular Biaryl Coupling Reaction of Cyclic Triamide Derived from N-Alkylated 4-Amino-2-bromobenzoic Acid (Fac. Sci. and Technol., Seikei Univ.) º ISHII, Arisa; OHISHI, Tomoyuki; YOKOYAMA, Akihiro

3I3-11
Synthesis and device characteristics of extended π-conjugated electron-accepting molecules by introducing multiple cyano groups. (Grad. Sch. Eng., Nagoya Inst. of Tech.) º TSUKAMOTO, Kenji; TAKAGI, Koji; YUTAKA, Ie


Chair: HASHIKAWA, Yoshifumi (11:00-11:50)

* 10:50-11:00: interval for laptop PC connection.(3I3-13, 3I3-14, 3I3-15, 3I3-16, 3I3-17)

3I3-13
Intramolecular cyclization reaction of [7]-Thiaheterohelicene Derivative and Reactivities of Cyclized Product (Grad. Sch. Sys. Eng., Wakayama Univ.) º NAKANISHI, Tatsuya; OSUGA, Hideji; SAKAMOTO, Hidefumi

3I3-14
Synthesis of iptycenes utilizing aryne derived from triptycene (Grad. Sch. Eng. Sci., Kyushu Univ.) º FUKAMI, Takuto; IWATA, Takayuki; SHINDO, Mitsuru

3I3-15
Synthesis of Cage-shaped Molecules Based on Syn- substituted Triptycenes (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) º YOSHINAGA, Tatsuro; IWATA, Takayuki; SHINDO, Mitsuru

3I3-16
Construction of a benzene ring connecting a carbonyl group and an aromatic ring via (5+1) annulation (Fac. Sci., Gakushuin Univ.) KINOSHITA, Hanae; º MOROFUJI, Tatsuya; KANO, Naokazu

3I3-17
Synthesis of the bridged indigos and evaluation of their functions (Grad. Sch. Life and Env. Sci., Kyoto Pref. Univ.) º KANDA, Junya; IMAYOSHI, Ayumi; TSUBAKI, Kazuori

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