The 99th Annual Meeting of The Chemical Society of Japan

Date: March 16th - 19th, 2019

Venue: Okamoto Campus, Konan University, Kobe, Japan

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Room D1

Bldg. 3 331


[Coordination Chemistry, Organometallic Chemistry]


Saturday, March 16, AM


Zn, Cu, Au

Chair: NAKAJIMA, Takayuki (09:00-09:40)

* 8:50-9:00: interval for laptop PC connection.(1D1-01, 1D1-02, 1D1-03, 1D1-04)

1D1-01
Design,Synthesis and Photoreactivity of Nanoporous Metal Complexes with Double Bonds (Sch. Eng., Nagoya Univ.) º ONO, Katsuya; KUSAKA, Shinpei; HORI, Akihiro; MA, Yunsheng; MATSUDA, Ryotaro

1D1-02
Influence of humidity for the Layer-by-layer film growth of MOFs (Sch. Mat. Sci., JAIST) º MATSUZAWA, Toshitaka; SUETSUGU, Kota; HARA, Mitsuo; NAGANO, Shusaku; NAGAO, Yuki

1D1-03
The Cu-catalyzed dearomatization / addition reaction of tertiary radical species at room temperature for the construction of contiguous quaternary carbons (Fac. Eng., Yamaguchi Univ.) º TSUCHIYA, Naoki; NISHIKATA, Takashi

1D1-04
Cu-catalyzed three-component reaction of styrenes, alcohols, and 2-bromocarbonyls (Grad. Sch. Sci. Tech., Yamaguchi Univ.) º MURATA, Yumi; SHIMADA, Taisei; NISHIKATA, Takashi


Saturday, March 16, PM

Chair: KUWABARA, Junpei (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(1D1-28, 1D1-30, 1D1-31, 1D1-32, 1D1-33)

1D1-28*#
Copper-Bipyridine-Catalyzed Stereospecific Intramolecular Suzuki-Miyaura Coupling of α-Aminoalkylboronic Esters (Grad. Sch. Eng., Kyoto Univ.) º YOSHINAGA, Yukako; YAMAMOTO, Takeshi; SUGINOME, Michinori

1D1-30#
Hydrogenation of CO2 Catalyzed by Dinuclear Copper Hydride Complexes (Fac. Sci., Nara Women's Univ.) º NAKAMAE, Kanako; NAKAJIMA, Takayuki; TANASE, Tomoaki

1D1-31
Reaction of Tetraaryldiborane(4) with Oxygen-Substituted Group 11 Complexes (Sch. Eng., Nagoya Univ.) º SUZUKI, Akane; YAMASHITA, Makoto

1D1-32
Preparation of new transition metal complexes with Au-Si bond from gold(I)-thiolate complex (Lab. Chem. Life Sci., Tokyo Tech.) º OKUMA, Kazuki; KANDA, Atsushi; TSUCHIDO, Yoshitaka; OSAKADA, Kohtaro


Ni, Pd, Pt

1D1-33
Development of Ni(0) Complexes Bearing N-phosphinomethyl-substituted NHC Ligand for Catalytic Acrylate Salt Synthesis from Ethylene and CO2 (Sch. Sci., Tokyo Tech.) º IWAI, Asaki; CHO, Kinryo; TAKAHASHI, Kohei; IWASAWA, Nobuharu


Chair: YAMASHITA, Makoto (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(1D1-35, 1D1-36, 1D1-37, 1D1-38, 1D1-39, 1D1-40)

1D1-35
Synthesis and Reactivity of Nickel(I) Complexes Bearing Bulky NHC/Phosphine Mixed Ligands (Fac. Sci., Fukuoka Univ.) º FUJII, Takahiro; INATOMI, Takahiro; KOGA, Yuji; MATSUBARA, Kouki

1D1-36#
Rapid 11C-Cyanation of (Hetero)arylstannanes Mediated by Combined Use of Pd and Cu Complexes (RIKEN BDR) º ZHANG, Zhouen; NIWA, Takashi; WATANABE, Yasuyoshi; HOSOYA, Takamitsu

1D1-37
Synthesis of Air-Stable Pd(0) Catalyst Precursor Bearing Different Kinds of Phosphine Ligands (TREMS, Univ. of Tsukuba) º SATO, Ryota; KUWABARA, Junpei; KANBARA, Takaki

1D1-38#
Design and Synthesis of Novel Palladium/Phosphine-Sulfonate Catalysts for Highly Stereospecific Polymerization of Propylene (Grad. Sch. Eng., The Univ. of Tokyo) º TOMIZAWA, Izumi; KENGOYAMA, Chihiro; ITO, Shingo; NOZAKI, Kyoko

1D1-39
Development of Visible Light-driven Catalytic Carboxylation of Aryl/Alkenyl Triflates with CO2 Using Pd/Photoredox Dual Catalysts (Sch. Sci., Tokyo Tech.) º NAKAJIMA, Tomoya; HONDA, Jun; CANER, Joaquim; TORIUMI, Naoyuki; IWASAWA, Nobuharu

1D1-40
Palladium-catalyzed Aldehyde-selective Wacker-type Oxidation of Aliphatic Terminal Alkenes (Fac. Sci., Nara Women's Univ.) º KOMORI, Saki; YAMAGUCHI, Yoshiko; KATAOKA, Yasutaka; URA, Yasuyuki


Chair: URA, Yasuyuki (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(1D1-42, 1D1-43, 1D1-44, 1D1-45, 1D1-46, 1D1-47)

1D1-42
Mechanistic study of Pd/Ag-mediated cross dehydrogenative coupling (CDC) and clarification of roles of Ag salts (TREMS, Univ. of Tsukuba) º SHIMOYAMA, Yuto; KUWABARA, Junpei; KANBARA, Takaki

1D1-43
Synthesis and Structures of mono- and trinuclear Palladium Complexes Bearing Cyclononatetraenyl (Sch. Mater. & Chem. Tech., Tokyo Tech.) º MORIDAIRA, Risako; YAMAMOTO, Koji; MURAHASHI, Tetsuro

1D1-44
Selective Synthesis of Group 10 Transition Metal Complexes and Clusters Consisting of Organogermanium Moieties (Grad. Sch. Eng., The Univ. of Tokyo) º KATO, Misaki; SUNADA, Yusuke

1D1-45
Synthesis and Structure of Mono- and Dinuclear Pd(I) Complexes Containing Bidentate Phosphine Ligands (Sch. Mater. & Chem. Tech., Tokyo Tech.) º SASAKI, Kota; YAMAMOTO, Koji; MURAHASHI, Tetsuro

1D1-46
Construction of Heptanuclear Palladium Clusters Based on the Insertion of Metal Precursor into Si-Si Bonds of Cyclic Polysilanes (Grad. Sch. Eng., The Univ. of Tokyo; IIS, The Univ. of Tokyo) º SHIMAMOTO, Kento; SUNADA, Yusuke

1D1-47#
Preparation and Dynamic Behavior of Triplatinum Complex with Bridging Si and Ge Ligands (Lab. Chem. Life Sci., Tokyo Tech.) º DING, Siming; TSUCHIDO, Yoshitaka; KOIZUMI, Take-aki; OSAKADA, Kohtaro


Chair: YAMAMOTO, Koji (17:00-18:00)

* 16:50-17:00: interval for laptop PC connection.(1D1-49, 1D1-51, 1D1-52, 1D1-53, 1D1-54)

1D1-49*#
Accelerated ligand exchange of metal acetylides by using light-induced structural change (Grad. Sch. Arts and Sci., The Univ. of Tokyo) º KANEKO, Shunichi; MASAI, Hiroshi; TAMAKI, Takashi; TERAO, Jun


Co

1D1-51
Hydrogenation of Haloalkanes by Metal-Ligand Coopration of a PNNP-Co complex (Advanced Industrial Science And Technology) º ISHIZAKA, Yusuke; NAKAJIMA, Yumiko

1D1-52
Synthesis and Reactivity of Cobalt-Aluminum Bimetallic Complexes (Grad. Sch. Eng., Kyoto Univ.) º SHIMOURA, Fumiya; SEMBA, Kazuhiko; NAKAO, Yoshiaki

1D1-53#
Syntheses and Reduction of Cobalt Complexes Bearing a Sterically Demanding Phenanthroline-based Ligand (Grad. Sch. Eng. Sci., Osaka Univ.) º UEDA, Yohei; TSURUGI, Hayato; MASHIMA, Kazushi

1D1-54
Regioselective hydrosilylation of aliphatic olefins catalyzed by cobalt complexes (Grad. Sch. Sci., Osaka City Univ.) º TAGUCHI, Daisuke; KOBAYASHI, Katsuaki; MORIUCHI, Toshiyuki; NAKAZAWA, Hiroshi


Chair: SATOH, Tetsuya (18:10-18:40)

* 18:00-18:10: interval for laptop PC connection.(1D1-56)

1D1-56 Young Scholar Lectures of CSJ#
Catalytic Asymmetric C-H functionalization by high-valent group 9 metals (Grad. Sch. Pharm., Hokkaido Univ.) º YOSHINO, Tatsuhiko


Sunday, March 17, AM


Rh, Ir

Chair: KUWATA, Shigeki (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(2D1-01, 2D1-02, 2D1-03, 2D1-04, 2D1-05, 2D1-06)

2D1-01
Development of highly active chiral Rh catalyst for asymmetric 1,4-addition using interplay between calculations and experiments (Iwate Univ.) º KORENAGA, Toshinobu; SASAKI, Ryo; MORIYA, Satsuki

2D1-02
Hydrosilylation of allyl chloride catalyzed by a Rh complex bearing a bidentate-phosphine ligand (IRC3, AIST) º INOMATA, Koya; SATO, Kazuhiko; NAKAJIMA, Yumiko

2D1-03
Synthesis and Reactivity of Pyrrole-Based PNP Pincer-Rhodium Complexes (Grad. Sch. Eng., The Univ. of Tokyo) º KAWAKAMI, Ryosuke; ARASHIBA, Kazuya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

2D1-04
Synthesis and Reactivity of Rhodium and Iridium Hydride Complexes Having Pincer Type, Low Valent Group 13 Metalloligands (Sch. Sci., Tokyo Tech.) º HOSHINO, Mayuko; UEKI, Kanako; TAKAYA, Jun; IWASAWA, Nobuharu

2D1-05
Synthesis and Properties of Metallophosphine-ligated Iridium Hydride Complexes (Grad. Sch. Sci., Osaka Pref. Univ.) º SAKAUE, Naoki; TAKEMOTO, Shin; MATSUZAKA, Hiroyuki

2D1-06
Stereospecific visible light-induced oxidative additions of π-coordinated alkenylsilanes (Fac. Sci., Nara Women's Univ.) º ITAKURA, Ayaka; URA, Yasuyuki; KATAOKA, Yasutaka


Ir

Chair: NAKAJIMA, Yumiko (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(2D1-08, 2D1-09, 2D1-10, 2D1-11, 2D1-12)

2D1-08
Synthesis and photocatalytic activity of dinuclear iridium hydride complexes having BINAP ligands. (Grad. Sch. Sci., TMU) º SOFUE, Yuki; NOMURA, Kotohiro; INAGAKI, Akiko

2D1-09#
Photocatalytic hydrogenation of carbon dioxide by trinuclear hydride complex containing light absorbing diphosphine ligand (Fac. Sci., TMU) SHITAYA, Shoji; NOMURA, Kotohiro; º INAGAKI, Akiko

2D1-10
Carboxylative cyclization of unsaturated amines with iridium complexes bearing a proton-responsive site at the β-position to the metal (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TSUDA, Yuto; KAYAKI, Yoshihito; KUWATA, Shigeki

2D1-11
Synthesis and Reactivities of Half-sandwich-type Iridium Complexes Bearing Benzoquinone Dioxime Ligand (Sch. Mater. & Chem. Tech., Tokyo Tech.) TAKAMURA, Taishin; º HARADA, Takuya; KUWATA, Shigeki

2D1-12*#
Site- and enantioselective C−H borylation of cyclic amines by cooperative iridium/aluminum catalysis (Grad. Sch. Eng., Kyoto Univ.) º KURODA, Yusuke; YADAV, Ramu; PARK, Kyungho; SHIRAISHI, Hiroshi; RONG-LIN, Zhong; SAKAKI, Shigeyoshi; NAKAO, Yoshiaki


Chair: KODERA, Masahito (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(2D1-15, 2D1-16, 2D1-17, 2D1-18, 2D1-19, 2D1-20)

2D1-15
Synthesis, Structures, and Reactivity of Iridium Complexes Having Silyl-NHC Chelate Ligands (Sch. Sci., Tohoku Univ.) º SAKURABA, Kanta; KOMURO, Takashi; TOBITA, Hiromi

2D1-16
Oxidation of an Alkyne by O2 at Group 9 Metal Complexes with a Pyridylphenyl Ligand (Grad. Sch. Sci. Eng., Chuo Univ.) º NAMBA, Takayuki; AKIYAMA, Seiji; KUWABARA, Takuya; KODAMA, Shintaro; ISHII, Youichi

2D1-17
Synthesis and catalytic application of P-Al-P pincer Ir complexes (Grad. Sch. Eng., Nagoya Univ.) º MORISAKO, Shogo; WATANABE, Seiya; YAMASHITA, Makoto

2D1-18
Synthesis and Structure of Late-Metal Complexes Bearing a Tetra(NHC) Macrocyclic Ligand (Grad. Sch. Eng., Nagoya Univ.) º KOMORI, Ayaka; ITO, Jun-ichi; YAMASHITA, Makoto

2D1-19
Synthesis, Structure, and Reactivity of a Silanthione-coordinated Iridium Complex with Two Phenyl Groups on the Silicon Atom (Grad. Sch. Sci. Tech., Hirosaki Univ.) º CHIBA, Yuya; OHTANI, Ryusuke; OHTA, Shun; OKAZAKI, Masaaki

2D1-20
Synthesis, Structures, and Properties of Cationic Half-sandwich-type Group 4 Transition-metal Hydrosilylamido Complexes (Grad. Sch. Sci. Tech., Hirosaki Univ.) º HOSHIBA, Yuki; OHTA, Shun; OKAZAKI, Masaaki


Sunday, March 17, PM


Ir, Pt

Chair: NAKAJIMA, Kazunari (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(2D1-28, 2D1-29, 2D1-30, 2D1-31, 2D1-32, 2D1-33)

2D1-28
Electroreduction of Carbon Dioxide to Formate by Homogeneous Ir Catalysts in Water (RIEF, AIST) º KANEGA, Ryoichi; ONISHI, Naoya; HIMEDA, Yuichiro

2D1-29#
Effect of ligands and sacrificial reagents for CO2 photoreduction using an iridium complex as a photocatalyst (Grad. Sch. Sci., Nagoya Univ.; Toyota Central R&D Labs., Inc.) º KAMADA, Kenji; JUNG, Jieun; SEKIZAWA, Keita; SATO, Shunsuke; MORIKAWA, Takeshi; SAITO, Susumu

2D1-30
Mechanistic Studies on Formation of Dinuclear Complexes Triggered by Coordination of P-alkyne-P Tridentate Ligands to Rh(I) or Ir(I) Precursors (Grad. Sch. Eng., Kyoto Univ.) º SASAKURA, Kohei; OKAMOTO, Kazuhiro; OHE, Kouichi

2D1-31
Synthesis of N-Tethered Iridium Complexes Having N-Sulfonyldiamine Linked to a Cp* Ligand (Sch. Mater. & Chem. Tech., Tokyo Tech.) º YOSHIDA, Minori; KUWATA, Shigeki; KAYAKI, Yoshihito

2D1-32
Synthesis of Carbene-bridged Dinuclear Iridium Complexes through Double CH Activation of Bisphenol Derivatives (Grad. Sch. Sci. Eng., Chuo Univ.) º TORIUMI, Takuya; ISHIKAWA, Mikiya; KUWABARA, Takuya; KODAMA, Shintaro; ISHII, Youichi

2D1-33#
Metal-Ligand Cooperative C-H Bond Formation and Cleavage by Cyclopentadienone Platinum Complexes (Grad. Sch. Eng., The Univ. of Tokyo) º HIGASHI, Takuya; ANDO, Hideaki; KUSUMOTO, Shuhei; NOZAKI, Kyoko


Ru

Chair: TAKEMOTO, Shin (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(2D1-35, 2D1-36, 2D1-37, 2D1-38, 2D1-39, 2D1-40)

2D1-35
Behavior of Bidentate Ligand in Bis(protic dihydropyridylidene) Ruthenium Complexes (Sch. Mater. & Chem. Tech., Tokyo Tech.) º KURASHIMA, Kenta; KAYAKI, Yoshihito; KUWATA, Shigeki

2D1-36
C-O Bond Cleavage of Unsaturated Alcohols by β-Protic Ruthenium Complexes (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TASHIMA, Naoto; KUWATA, Shigeki

2D1-37
Integration of Ruthenium Complexes with a Non-chelating Diphosphine Ligand and Its Function (Sch. Mater. & Chem. Tech., Tokyo Tech.) º SUZUKI, Satoshi; TODA, Tatsuro; KUWATA, Shigeki

2D1-38
Ruthenium-catalyzed oxidative conversion of ammonia into dinitrogen (Grad. Sch. Eng., The Univ. of Tokyo; Fac. Pharm. Sci., Toho Univ.) º TODA, Hiroki; NAKAJIMA, Kazunari; SAKATA, Ken; NISHIBAYASHI, Yoshiaki

2D1-39
Studies on Reactive Intermediates of Ruthenium-Catalyzed Ammonia Oxidation Reaction (Grad. Sch. Eng., The Univ. of Tokyo; Fac. Pharm. Sci., Toho Univ.) º TODA, Hiroki; NAKAJIMA, Kazunari; SAKATA, Ken; NISHIBAYASHI, Yoshiaki

2D1-40
Quantum Chemical Study on Ruthenium-Catalyzed Oxidation Reaction of Ammonia into Dinitrogen (Fac. Pharm. Sci., Toho Univ.; Grad. Sch. Eng., The Univ. of Tokyo) º SAKATA, Ken; TODA, Hiroki; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki


Chair: HIRANO, Masafumi (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(2D1-42, 2D1-43, 2D1-44, 2D1-46, 2D1-47)

2D1-42
Selective Synthesis of Heterometallic Clusters Using Dianionic Diruthenium(II) Bis(imido) Complex as Template (Grad. Sch. Sci., Osaka Pref. Univ.) º OYABU, Tomofumi; TAKEMOTO, Shin; MATSUZAKA, Hiroyuki

2D1-43
Catalytic disproportionation of formic acid to methanol with multinuclear ruthenium complexes (Grad. Sch. Sci., Osaka Pref. Univ.) º FUJITA, Hiroaki; TAKEMOTO, Shin; MATSUZAKA, Hiroyuki

2D1-44*#
Unusual Rearrangement of a Modified PNP Ligand based Ru Complexes (OIST) º DEOLKA, Shubham; KHASKIN, Eugene

2D1-46
Investigation of substituent effect in ruthenium-catalyzed ammonia oxidation reaction (Grad. Sch. Eng., The Univ. of Tokyo) º UEMA, Koyo; TODA, Hiroki; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

2D1-47
Investigation of the ligand effect on cross metathesis with tetrafluoroethylene by ruthenium catalyst (Grad. Sch. Eng., The Univ. of Tokyo) º MORI, Kenta; AKIYAMA, Midori; TAKAHIRA, Yusuke; OTOZAWA, Nobuyuki; OKAZOE, Takashi; NOZAKI, Kyoko


Ru, Fe

Chair: KAYAKI, Yoshihito (17:00-17:40)

* 16:50-17:00: interval for laptop PC connection.(2D1-49, 2D1-50, 2D1-51, 2D1-52)

2D1-49#
Synthesis and Properties of Anionic Ruthenium Complexes with a Selenonitrosyl Ligand (Grad. Sch. Sci., TUS) º FUNG, Chi-wai; FUKADA, Go; TSUCHIDA, Noriko; MUTOH, Yuichiro; SAITO, Shinichi

2D1-50
Synthesis and Chromic Behaviors of Ruthenium Disubstituted Vinylidene Complexes with Group 15/16 Element Substituents (Grad. Sch. Sci. Eng., Chuo Univ.) º SAKAJIRI, Kosuke; AOKI, Yutaka; DEGUCHI, Kazuki; KUWABARA, Takuya; HOUJOU, Hirohiko; ISHII, Youichi

2D1-51
Catalytic Synthesis of Conjugated Trienes from Unsymmetrical Internal Alkynes and Conjugated Dienes: Electronic and Steric Effects of Substituents on the Regioselectivity (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º KIYOTA, Sayori; HIRANO, Masafumi

2D1-52
Catalytic Activity of Iron Complex with Tetradentate Phosphorus Ligand for Polymerization of Hydrosilane (Grad. Sch. Sci., Osaka City Univ.) º DONAKA, Yosuke; ITAZAKI, Masumi; MORIUCHI, Toshiyuki; NAKAZAWA, Hiroshi


Monday, March 18, AM


Fe

Chair: NISHIMOTO, Yoshihiro (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(3D1-01, 3D1-02, 3D1-03, 3D1-04, 3D1-05, 3D1-06)

3D1-01
Synthesis and Reduction of Iron and Cobalt Complexes of 1,1’-Bis(arylamide)vanadocenes (Grad. Sch. Sci., Osaka Univ.; Sch. Sci., Tokyo Tech.) º KUSUNOSE, Hinano; HATANAKA, Tsubasa; KAWAGUCHI, Hiroyuki; FUNAHASHI, Yasuhiro

3D1-02
Development of 3d late transition metal complexes by using the organogermanium anions (IIS, The Univ. of Tokyo) º KOBAYASHI, Yoshinao; SUNADA, Yusuke

3D1-03
Cleavage of a Si-Cl bond of chlorosilanes by iron(0) complex bearing a tetradentate-PNNP ligand (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º TAKESHITA, Tomohiro; NAKAJIMA, Yumiko

3D1-04
Synthesis of a Cubans-Type [Mo3S4Fe] Cluster Supported by C5Me4SiEt3 Ligands and its Application in the Catalytic Silylation of N2 (Sch. Sci., Nagoya Univ.) º MUNAKATA, Kenichiro; HARA, Ryouta; TADA, Mizuki; TAKAYAMA, Tsutomu; SAKAI, Yoichi; OHKI, Yasuhiro

3D1-05
Synthesis of Multi-Nuclear Fe Clusters from the Reaction of an Fe(II) amide complex with PtBu3 and HBpin (Sch. Sci., Nagoya Univ.) º OISHI, Shunya; TADA, Mizuki; OHKI, Yasuhiro

3D1-06
Synthesis and Reactivity of Iron-Dinitrogen Complexes Bearing Anionic Benzene-Based PCP-Type Pincer Ligands (Grad. Sch. Eng., The Univ. of Tokyo) º KATO, Takeru; ARASHIBA, Kazuya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki


B

Chair: OOHASHI, Masato (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(3D1-08, 3D1-09, 3D1-10, 3D1-12)

3D1-08
Ni/Ir-cocatalyzed photoredox coupling utilizing a recyclable organoboron compound (RIKEN BDR) º SUMIDA, Yuto; SUMIDA, Tomoe; RIKITAKE, Midori; HASHIZUME, Daisuke; HOSOYA, Takamitsu

3D1-09#
Electronic and Steric Controls of Catalytic Activity of Cage-Shaped Borates by Various Aryl Groups Surrounding the Boron Center (Grad. Sch. Eng., Osaka Univ.) º TANAKA, Daiki; KONISHI, Akihito; YASUDA, Makoto

3D1-10*#
Synthesis and reactivity of borata-alkene derivative bearing a phosphine moiety (Univ. of Muenster) º WATANABE, Kohei; UENO, Atsushi; DANILIUK, Constantin; GERALD, Kehr; GERHARD, Erker

3D1-12*#
A novel rigid bidentate B/P ligand: Synthesis and Coordination Chemistry (Grad. Sch. Eng., The Univ. of Tokyo) º SEIDEL, Falk William; NOZAKI, Kyoko


Al, Si

Chair: IWASAKI, Takanori (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(3D1-15, 3D1-17, 3D1-18, 3D1-19, 3D1-20)

3D1-15*#
Synthesis and Characterization of Pheox- and Phebox-Al Complexes and Its Application to the Lewis Acid Catalyzed Reactions (Grad. Sch. Eng., Osaka Univ.) º NAKAO, Shuichi; NISHIMOTO, Yoshihiro; YASUDA, Makoto

3D1-17
Catalytic Asymmetric Cyanosilylation Reaction of Aldehydes by Self-assembly Al(III)-salen Complex (Grad. Sch. Eng., TUS) º MASUNAGA, Kazumi; IMAHORI, Tatsushi

3D1-18
Formation of Polyanions of Ladder Oligosilanes and Related Compounds (Grad. Sch. Sci. Tech., Gunma Univ.) º NOMURA, Ryunosuke; KYUSHIN, Soichiro

3D1-19
Synthesis, Structure, and Reactivity of Silyl- and Alkyl-substituted Disilene (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º HIBI, Fuya; NABESHIMA, Tatsuya; ICHINOHE, Masaaki

3D1-20
Generation of Alkyl-substituted 1,2-Dilithiodisilane (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º TOJO, Shoma; NABESHIMA, Tatsuya; ICHINOHE, Masaaki


Monday, March 18, PM


Si, Ge, Sn

Chair: ISHIDA, Shintaro (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(3D1-28, 3D1-29, 3D1-30, 3D1-31, 3D1-32, 3D1-33)

3D1-28
Synthesis of Disilene Dianion Using Extend Triptycyl Frameworks (Coll. Sci., Rikkyo Univ.) º NISHINO, Ryohei; MINOURA, Mao

3D1-29
Synthesis of Heavy Phenoxide (ICR, Kyoto Univ.) FUJIMORI, Shiori; º MIZUHATA, Yoshiyuki; TOKITOH, Norihiro

3D1-30
Synthetic studies of 1-germaazulene (ICR, Kyoto Univ.) º OSHIRO, Taku; MIZUHATA, Yoshiyuki; TOKITOH, Norihiro

3D1-31
Structure of Group 14 Allyl Metals and Mechanistic Study for Allylation of Aldehydes Using Allylgermanes (Graduate School of Engineering, Osaka University) MINAMI, Yohei; º NISHIDA, Kento; KONISHI, Akihito; YASUDA, Makoto

3D1-32
Synthesis and Reactions of Methylene-substituted Germylene (ICR, Kyoto Univ.) º YUKIMOTO, Mariko; TOKITOH, Norihiro

3D1-33
Synthesis and Reactivity of a Stannacycloheptatrienylidene (Grad. Sch. Sci. Eng., Chuo Univ.) º ITO, Shotaro; KUWABARA, Takuya; ISHII, Youichi


Sn, In, Li

Chair: MINOURA, Mao (14:40-15:20)

* 14:30-14:40: interval for laptop PC connection.(3D1-35, 3D1-36, 3D1-37, 3D1-38)

3D1-35
Synthesis and Structure of Tetrastannacyclobutadiene (Grad. Sch. Sci. Eng., Kindai Univ.) º NUMATA, Yasuyuki; SADAMORI, Kazuya; HATANAKA, Miho; MATSUO, Tsukasa

3D1-36
Tin Alkoxide-catalyzed Annulation Between Mercaptoketones and Activated Alkenes (Grad. Sch. Eng., Osaka Univ.) º SAKAMOTO, Yuki; SUZUKI, Itaru; SHIBATA, Ikuya

3D1-37
Indium Hydride-Catalyzed Reductive Coupling of Conjugated Dienes with Ketones via Hydroindation of Unsaturated Bonds (Grad. Sch. Eng., Osaka Univ.; Res. Cent. Environ. Preserv., Osaka Univ.) º YAGI, Kensuke; SUZUKI, Itaru; SHIBATA, Ikuya

3D1-38
Development of Stimuli-Responsive Li-BINOLate Catalyst (Grad. Sch. Eng., TUS) º NOJIRO, Yuta; OHASHI, Satoshi; IMAHORI, Tatsushi


Tuesday, March 19, AM


Si

Chair: NANJO, Masato (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(4D1-01, 4D1-02, 4D1-03, 4D1-05)

4D1-01
Synthesis and properties of a novel dialkylsilylene (Grad. Sch. Sci., Tohoku Univ.) º KOBAYASHI, Ryo; ISHIDA, Shintaro; IWAMOTO, Takeaki

4D1-02
Synthesis of a Tetrasilabicyclo[1.1.0]butane Bearing Arylthio Substituents on the Bridgehead Silicons (Grad. Sch. Sci., Tohoku Univ.) º NUKAZAWA, Takumi; ISHIDA, Shintaro; IWAMOTO, Takeaki

4D1-03*#
Functionalization of 1-Iodobicyclo[1.1.1]pentasilanes at the Bridgehead Position (Grad. Sch. Sci., Tohoku Univ.) º YOKOUCHI, Yuki; IWAMOTO, Takeaki

4D1-05*#
Precise Synthesis of Macrocyclic Polysiloxanes with Si-H Group (IRC3, AIST) º KAWATSU, Takahiro; MATSUMOTO, Kazuhiro; CHOI, Jun-chul; SATO, Kazuhiko


Chair: SAKAMOTO, Kenkichi (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(4D1-08, 4D1-10, 4D1-11, 4D1-12, 4D1-13)

4D1-08*#
Coordination chemistry of iminophosphonamido silylene (Grad. Sch. Sci., Eng., Saitama Univ.) º TAKAHASHI, Shintaro; NAKAYA, Kazuki; NAKATA, Norio; ISHII, Akihiko

4D1-10
Development of nickel-catalyzed cross coupling of chlorosilanes with organoaluminum reagents (IRC3, AIST) º NAGANAWA, Yuki; GUO, Haiqing; SAKAMOTO, Kei; NAKAJIMA, Yumiko

4D1-11
Ruthenium-Catalyzed Hydrosilylation of 1,3-Dienes with Various Hydrosilanes in the Presence of Ruthenium Catalysts (Grad. Sch. Sci. Tech., Gunma Univ.) º NOGUCHI, Seiya; KANNO, Ken-ichiro; KYUSHIN, Soichiro

4D1-12
Effects of a Phosphorus Atom on Electronic States of Silicon Clusters (Grad. Sch. Sci. Tech., Gunma Univ.) º TSUMURAYA, Tomohiro; KYUSHIN, Soichiro

4D1-13
Synthesis and Property of Cationic Tris(iminophosphonamidesilylene)-Iridium Complex (Grad. Sch. Sci., Eng., Saitama Univ.) º NAKAYA, Kazuki; TAKAHASHI, Shintaro; NAKATA, Norio; ISHII, Akihiko


Chair: NAKATA, Norio (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(4D1-15, 4D1-16, 4D1-17, 4D1-18, 4D1-19, 4D1-20)

4D1-15
Synthesis and Properties of Novel Ionic Liquids with Siloxane Unit in the Sulfonate Ion (Grad. Sch. Eng., Tottori Univ.) º OTA, Masakazu; ARITA, Chihiro; NANJO, Masato

4D1-16
Synthesis of novel halogen-free ionic liquids based on silicon-containing borate as a counter ion (Grad. Sch. Eng., Tottori Univ.) º KASAHARA, Kenta; NAGASAKI, Kosuke; NANJO, Masato

4D1-17
Synthesis and Reactions of alkoxy-substituted hexahydrosilaphenalene (Fac. Sci., Shizuoka Univ.) º FURUSAWA, Ayaka; TAKAGI, Haruka; OKA, Shohei; SUGINO, Takumi; SAKAMOTO, Kenkichi

4D1-18
The synthesis of functionalized oligosilanes using a (tert-butoxy)disilanyl]lithium (Grad. Sch. Sci., Eng., Hosei. Univ.) º MATSUO, Takuya; KAWACHI, Atsushi

4D1-19
Synthesis of o-(Silyl)(boryl)benzenes with Borafluorenyl Group (Grad. Sch. Sci., Eng., Hosei. Univ.) º SHIMIZU, Tomomi; KAWACHI, Atsushi

4D1-20
Reactions of 1,2-Dihaloditetrenes Bearing the Rind Groups (Grad. Sch. Sci. Eng., Kindai Univ.) º OHNO, Ryoma; KONAKA, Shigeaki; NUMATA, Yasuyuki; HAYAKAWA, Naoki; ROSAS-SANCHEZ, Alfredo; HASHIZUME, Daisuke; MATSUO, Tsukasa


Tuesday, March 19, PM


Fe, Mn, Mo

Chair: MURAOKA, Takako (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(4D1-28, 4D1-29, 4D1-30, 4D1-32, 4D1-33)

4D1-28
Iron(II) triazolylidene complexes and catalytic hydrosilylation of aromatic aldehydes (Fac. Sci., Fukuoka Univ.) º IKEDA, Hayao; KOGA, Yuji; MATSUBARA, Kouki

4D1-29
Construction and reactions of coordinatively unsaturated manganese(II) and iron(II) silyl complexes (Grad. Sch. Eng., The Univ. of Tokyo) º ARATA, Shogo; SUNADA, Yusuke

4D1-30*#
Photochemical Synthesis of a Molybdenum Germylyne Complex and Its Catalytic Activity for Hydrosilylation of Aldehydes and Ketones (Grad. Sch. Sci., Tohoku Univ.) º DHUNGANA, Tara Prasad; HASHIMOTO, Hisako; TOBITA, Hiromi

4D1-32
Synthesis and Reactivity of Dinuclear Molybdenum Complexes Bridged by Ferrocene Skeleton (Grad. Sch. Eng., The Univ. of Tokyo) º ITABASHI, Takayuki; ARASHIBA, Kazuya; EIZAWA, Aya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

4D1-33
Isomerization of the Reaction Products of a Hydrogen-Bridged Bis(silylene) Molybdenum Complex with Carbodiimides (Grad. Sch. Sci., Tohoku Univ.) º YUTO, Kobayashi; HISAKO, Hashimoto; HIROMI, Tobita


Mo, W, Ti

Chair: TSURUGI, Hayato (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(4D1-35, 4D1-37, 4D1-38, 4D1-39, 4D1-40)

4D1-35*#
Transition Metal-Catalyzed Ammonia Formation by Using Alcohols and Water as Proton Sources (Grad. Sch. Eng., The Univ. of Tokyo) º ASHIDA, Yuya; ARASHIBA, Kazuya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

4D1-37
Substituent Effect on Catalytic Reduction of Dinitrogen to Ammonia by Using Alcohols and Water as Proton Sources. (Grad. Sch. Eng., The Univ. of Tokyo) º MIZUSHIMA, Takuro; EIZAWA, Aya; ASHIDA, Yuya; ARASHIBA, Kazuya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

4D1-38
Synthesis and Structure of a {Mesityl(methyl)silanone}tungsten Complex and its Reaction with PMe3 (Grad. Sch. Sci. Tech., Gunma Univ.) º ISHITA, Taichi; MURAOKA, Takako; UENO, Keiji

4D1-39
A steric effect of trimethylsilyl group toward the structures and the solution dynamics of bis(indolyl)-coordinated group IV transition metal diamido complexes (Fac. Sci. Tech., Hirosaki Univ.; Grad. Sch. Sci. Tech., Hirosaki Univ.) º TAKAHASHI, Shiona; AKAZAWA, Yuta; MIYAMOTO, Ryo; OKAZAKI, Masaaki; OHTA, Shun

4D1-40
Synthesis, Structures, and Reactivity of a Bis(indolyl)-coordinated Titanium Dichlorido Complex (Grad. Sch. Sci. Tech., Hirosaki Univ.) º OHTA, Shun; MIURA, Narumi; MIYAMOTO, Ryo; OKAZAKI, Masaaki


Ti, Sc, Y, Ce

Chair: SUNADA, Yusuke (15:50-16:40)

* 15:40-15:50: interval for laptop PC connection.(4D1-42, 4D1-44, 4D1-45, 4D1-46)

4D1-42*
Dinitrogen Activation by Titanium Complexes Bearing an (ONO)-Ligand (Sch. Sci., Tokyo Tech.) º ISHIDA, Yutaka; HASEGAWA, Sui; KAWAGUCHI, Hiroyuki

4D1-44#
Synthesis of Allylated N,N-Dimethlyanilines by Scandium-Catalyzed C−H Addition of 2-Methyl Anilines to Internal Alkynes (Organometallic Chem. Lab., RIKEN) º ZHOU, Wei; MASAYOSHI, Nishiura; HOU, Zhaomin

4D1-45
Synthesis and structure of organoyttrium complexes with a biphenolate ligand: stereoregular polymerization of 2-vinylpyridine (Sch. Mater. & Chem. Tech., Tokyo Tech.; Grad. Sch. Bioagr. Sci., Nagoya Univ.) º OISHI, Masataka; YOSHIMURA, Reiji; NOMURA, Nobuyoshi

4D1-46
Synthesis of cerium(III) complexes bearing diethylenetriamine ligands as catalysts for hydrosilylation of carbonyl compounds (Grad. Sch. Eng. Sci., Osaka Univ.) º SHINOHARA, Koichi; TSURUGI, Hayato; MASHIMA, Kazushi

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