The 95th Annual Meeting of The Chemical Society of Japan

Date: March 26th - 29th, 2015

Venue: Funabashi Campus, College of Science and Technology, Nihon University / School of Pharmacy, Nihon University, Chiba, Japan

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Room E5

Bldg.10 1042


[Organic Chemistry -Reaction and Synthesis- Organometallic Compounds]


Thursday, March 26, AM


Ir

Chair: SEMBA, Kazuhiko (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(1E5-05, 1E5-06, 1E5-07, 1E5-08, 1E5-09)

1E5-05
Iridium-Catalyzed Annelation of 2-Arylbenzoic Acids and Alkynes (Osaka Univ. Graduate School of Engineering) º NAGATA, Tomoya; HIRANO, Koji; SATOH, Tetsuya; MIURA, Masahiro

1E5-06
Iridium-Catalyzed Regioselective C-H Silylation Controlled by Lewis Acid-Base Interaction (Grad. Sch. Pharm., The Univ. of Tokyo) º WAKAKI, Takayuki; KANAI, Motomu; KUNINOBU, Yoichiro

1E5-07
Asymmetric Transfer Hydrogenation Catalyzed by New Chiral Bicyclic NHC/Ir Complexes (Grad. Sch. Sci., Chiba Univ.) º KAMIMURA, Takumi; KUWABARA, Hiroshi; YOSHIDA, Kazuhiro; YANAGISAWA, Akira

1E5-08
Asymmetric Hydrogenation of Quinazolinium Salts Catalyzed by Dinuclear Iridium (III) Complex Bearing Chiral Diphosphine Ligand (Grad. Sch. Eng. Sci., Osaka Univ.) º HIGASHIDA, Kosuke; IIMURO, Atsuhiro; KITA, Yusuke; MASHIMA, Kazushi

1E5-09
Hydrogen Bond-Controlled meta-Selective C-H Borylation of Aromatic Compounds (The Univ. of Tokyo Graduate School of Pharmaceutical Sciences, ERATO-JST) º NISHI, Mitsumi; IDA, Haruka; KUNINOBU, Yoichiro; KANAI, Motomu


Chair: HIRANO, Koji (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(1E5-11, 1E5-12, 1E5-13, 1E5-14, 1E5-15)

1E5-11
Iridium-catalyzed enantioselective [3 + 2] annulation of α-oxocarboxamides with 1,3-dienes (Grad. Sch. Sci., Kyoto Univ.) º HATANO, Miyuki; NISHIMURA, Takahiro

1E5-12
A Simple One-Pot Procedure for N-Formylation and N-Methylation of Amines via Room-Temperature Hydrosilylation of CO2 Catalyzed by a PNP-pincer Type Phosphaalkene Iridium(I) Complex (ICR, Kyoto Univ.) º CHANG, Yung-hung; SASAKI, Daichi; TAGUCHI, Hiroomi; TAKEUCHI, Katsuhiko; OZAWA, Fumiyuki

1E5-13
Highly Stereoselective Synthesis of Tetrasubstituted CF3 Alkenes from Alkynes by Photoredox Catalysis (Chem. Res. Lab., Tokyo Tech) º TOMITA, Ren; KOIKE, Takashi; AKITA, Munetaka

1E5-14
Ir-Catalyzed ortho-C-H Borylation of Arylboronic Acids Masked by Removable Directing Group on the Boron Atom (Grad. Sch. Eng., Kyoto Univ.) º ISHIBASHI, Aoi; YAMAMOTO, Takeshi; SUGINOME, Michinori

1E5-15
Direct Synthesis of Dithienosiloles by Iridium-Catalyzed Dehydrogenative Cyclization (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º ISOBUCHI, Ryota; MITSUDO, Koichi; SUGA, Seiji


Chair: KITA, Yusuke (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(1E5-17, 1E5-18, 1E5-19, 1E5-20, 1E5-21)

1E5-17
Synthesis of DMF-protected Ir Nanoclusters and Their Use as Catalyst in Methylation with Methanol (Fac. Chem. Materials and Bioeng., Kansai Univ.) º OIKAWA, Kei; YANO, Hiroki; KAWASAKI, Hideya; OBORA, Yasushi

1E5-18
Synthesis of Carboxylic Acids through Dehydrogenation of Primary Alcohols in Water Catalyzed by Iridium Complexes (Kyoto Univ. Graduate School of Human and Environmental Studies) º TANAKA, Yuhi; YAMAGUCHI, Ryohei; FUJITA, Ken-ichi

1E5-19
Dehydrogenation of Polyhydric Alcohols Catalyzed by an Iridium Complex Bearing a Functional Bipyridonate Ligand (Kyoto Univ. Graduate School of Human and Environmental Studies) º NAGANO, Yuta; YAMAGUCHI, Ryohei; FUJITA, Ken-ichi

1E5-20
Selective C-4 Borylation of Pyridine by Iridium/Aluminum Cooperative Catalysis (Grad. Sch. Eng., Kyoto Univ.; CREST, JST) º YANG, Lichen; SAITO, Teruhiko; SEMBA, Kazuhiko; NAKAO, Yoshiaki

1E5-21
Cationic Iridium-Catalyzed Asymmetric [3 + 2] Annulation of Aromatic Ketimines with Alkynes via C-H Activation (Grad. Sch. Sci., Kyoto Univ.) º YAMAUCHI, Daisuke; NAGAMOTO, Midori; NISHIMURA, Takahiro


Thursday, March 26, PM


Rh

Chair: OKAMOTO, Kazuhiro (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(1E5-29, 1E5-30, 1E5-31, 1E5-32, 1E5-33, 1E5-34)

1E5-29
Rhodium-Catalyzed Direct Alkenylation of Phenylphosphine Sulfides (Osaka Univ. Graduate School of Engineering) º YOKOYAMA, Yuki; UNOH, Yuto; HIRANO, Koji; SATOH, Tetsuya; MIURA, Masahiro

1E5-30
1,3-Dithiane Directed Aromatic C-H Alkenylation Under Rh(III) Catalysis (Osaka Univ. Graduate School of Engineering) º UNOH, Yuto; HIRANO, Koji; SATOH, Tetsuya; MIURA, Masahiro

1E5-31
Enantioselective Synthesis of 3-Hydroxy-3,4-dihydropyridones by Sequential Action of Light and Rhodium on N-allyl-α-oxoamides (Grad. Sch. Eng., Kyoto Univ.) º MASUDA, Yusuke; NECAS, David; ISHIDA, Naoki; MURAKAMI, Masahiro

1E5-32
Rhodium-Catalyzed Synthesis of Multi-substituted Silylindenes via C-H Bond Activation and Their Fluorescence Properties (Grad. Sch. Pharm., The Univ. of Tokyo) º SUEKI, Shunsuke; KUNINOBU, Yoichiro

1E5-33
Rhodium-Catalyzed Asymmetric Hydroformylation of Styrenes with Formaldehyde (Grad. Sch. Mat. Sci., NAIST) MORIMOTO, Tsumoru; º FUJII, Tetsuji; MIYOSHI, Kota; KAKIUCHI, Kiyomi

1E5-34
Asymmetric Hydrogenation of Olefins Catalyzed by Halide-bridged Dinuclear Rhodium(III) Complex Bearing Chiral Diphosphine Ligand. (Grad. Sch. Eng. Sci., Osaka Univ.) º HIDA, Shoji; KITA, Yusuke; MASHIMA, Kazushi


Chair: KOCHI, Takuya (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(1E5-36, 1E5-37, 1E5-39, 1E5-40, 1E5-41)

1E5-36
Rhodium-Catalyzed Cross-Coupling of Aryl Carbamates with Organoboron Reagents via the Cleavage of a Carbon-Oxygen Bond (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º NAKAMURA, Keisuke; CHATANI, Naoto

1E5-37*
Rhodium-Catalyzed Borylation of Aryl Esters and Ethers through the Cleavage of a Carbon-Oxygen Bond (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º KINUTA, Hirotaka; HASEGAWA, Junya; CHATANI, Naoto


Ni

1E5-39
Nickel-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through the Cleavage of a Carbon-Oxygen Bond (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º ZHAO, Jiangning; KINUTA, Hirotaka; CHATANI, Naoto


Rh

1E5-40
Rhodium porphyrin catalyzed addition reaction of imine and indole (Grad. Sch. Eng., Kyoto Univ.) º HASEGAWA, Makoto; KURAHASHI, Takuya; MATSUBARA, Seijiro

1E5-41
Rhodium-catalyzed ring expansion of 1-vinylbenzocyclobutenols to β-tetralones (Grad. Sch. Eng., Kyoto Univ.) º ISHIKAWA, Norikazu; SAWANO, Shota; ISHIDA, Naoki; MURAKAMI, Masahiro


Chair: ISHIDA, Naoki (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(1E5-43, 1E5-45, 1E5-46, 1E5-47, 1E5-48)

1E5-43*
The Reaction of Aromatic Amides with α,β-Unsaturated Carbonyl Compounds Using a Bidentate Directing Group by a Rhodium Complex (Grad. Sch. Eng., Osaka Univ.) º SHIBATA, Kaname; CHATANI, Naoto

1E5-45
Rhodium-Catalyzed Reaction of Terminal Alkynes with tButylhydrazines Leading to Nitriles (Grad. Sch. Eng., Osaka Univ.) FUKUMOTO, Yoshiya; º TAMURA, Yuto; CHATANI, Naoto

1E5-46
Rhodium-Catalyzed anti-Markovnikov Addition of N,N-Disubstituted Hydrazines to Terminal Alkynes Leading to Hydrazones (Grad. Sch. Eng., Osaka Univ.) º KAMIYA, Motonobu; FUKUMOTO, Yoshiya; CHATANI, Naoto

1E5-47
Catalytic [2+2+2] Cycloaddition for the Synthesis of Multi-substituted Dibenzothiophenes and -phosphole Oxides (Sch. Advanced Sci. Eng., Waseda Univ.) º MATSUBARA, Riku; SATO, Tatsuki; TAHARA, Yu-ki; SHIBATA, Takanori

1E5-48
Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silicon-Bridged Arylpyridinones (Fac. Eng., The Univ. of Tokyo; Fac. Eng., The Univ. of Tokyo) º TAKANO, Ryo; SHINTANI, Ryo; NOZAKI, Kyoko


Chair: TOBISU, Mamoru (17:10-18:00)

* 17:00-17:10: interval for laptop PC connection.(1E5-50, 1E5-52, 1E5-53, 1E5-54)

1E5-50*
Synthesis of New P-Chiral Phosphine Ligands Using Optically Active Secondary Phosphine-boranes and Their Enantioinduction Ability (NIPPON CHEMICAL INDUSTRIAL CO., LTD. Research and Development division; Grad. Sch. Sci., Chiba Univ.) º HORIUCHI, Yumi; TAMURA, Ken; SUGIYA, Masashi; IMAMOTO, Tsuneo

1E5-52
Synthesis and Enantioinduction Ability of One-Hindered Quadrant Diphosphine Ligands (Nippon Chemical Industrial Co., Ltd. Research and Development Devision; Grad. Sch. Sci., Chiba Univ.; Grad. Sch. Sci., Tohoku Univ.) º IMAMOTO, Tsuneo; ZHANG, Zhenfeng; TAMURA, Ken; HORIUCHI, Yumi; SUGIYA, Masashi; GRIDNEV, Ilya

1E5-53
Rhodium-Catalyzed Introduction of α-Acylalkyl Groups on Arenes with Cyclic Alkenyl Carbonates via C-H Bond Cleavage (Fac. Sci. Tech., Keio Univ.) º HARA, Yusuke; KOCHI, Takuya; KAKIUCHI, Fumitoshi

1E5-54
Transformation Reactions via Oxidative Addition of Oxime Esters to Rhodium(I) Complexes and C-H Activation (Grad. Sch. Eng., Kyoto Univ.) º SHIMBAYASHI, Takuya; OKAMOTO, Kazuhiro; OHE, Kouichi


Friday, March 27, AM


Ir

Chair: KOIKE, Takashi (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(2E5-05, 2E5-07, 2E5-09)

2E5-05*
Iridium-Catalyzed Intermolecular Dehydrogenative Silylation of Polycyclic Aromatic Compounds without Directing Groups (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º MURAI, Masahito; TAKAMI, Keishi; TAKAI, Kazuhiko

2E5-07*
Effects of Salt Formation of Substrates on Ir-catalyzed Asymmetric Hydrogenation of Isoquinolines (Grad. Sch. Eng. Sci., Osaka Univ.) º KITA, Yusuke; YMAJI, Kenta; HIGASHIDA, Kosuke; IIMURO, Atsuhiro; MASHIMA, Kazushi

2E5-09
Development of Highly Active Ir(III)-PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases : Electronic Effect of Ligands and Influence of Chloride Ions (Grad. Sch. Eng., The Univ. of Tokyo) º AOKI, Wataru; WATTANAVININ, Natdanai; KUSUMOTO, Shuhei; NOZAKI, Kyoko


Chair: MURAI, Masahito (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(2E5-11, 2E5-12, 2E5-13, 2E5-14, 2E5-15)

2E5-11
Ir(I)-Catalyzed C2-Selective C-H Alkylation of Pyridine N-Oxides (Sch. Advanced Sci. Eng., Waseda Univ.) º TAKANO, Hideaki; SHIBATA, Takanori

2E5-12
Asymmetric Synthesis of γ-Amino Acids Initiated by Enantioselective C-H Bond Cleavage by a Chiral Ir(I)-Catalyst (Sch. Advanced Sci. Eng., Waseda Univ.) º MICHINO, Masamichi; ITO, Mamoru; TAHARA, Yu-ki; SHIBATA, Takanori

2E5-13
Synthesis of 3,3-Difluoropropiophenones through Oxidative Difluoromethylation of Styrenes by Photoredox Catalysis (Chem. Res. Lab., Tokyo Tech) º ANDO, Gaku; ARAI, Yusuke; KOIKE, Takashi; AKITA, Munetaka

2E5-14
Iridium-catalyzed Decarboxylative Ring Contraction of Isoxazole-5(4H)-ones. (Grad. Sch. Eng., Kyoto Univ.) OKAMOTO, Kazuhiro; º YOSHIDA, Masato; NANYA, Atsushi; SHIMBAYASHI, Takuya; OHE, Kouichi

2E5-15
The Synthesis of New Chiral 1,2,3-Triazol-5-ylidene Ligands and Application of Catalytic Asymmetric Transfer Hydrogenation (Fac. Sci. Eng., Chuo Univ.) º TOSAKA, Takuya; MITSUI, Takashi; TOKORO, Yuuichirou; FUKUZAWA, Shin-ichi


Chair: SUGINOME, Michinori (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(2E5-17, 2E5-18, 2E5-19)

2E5-17
Para-selective C-H borylation of benzene derivatives (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST) º SAITO, Yutaro; SEGAWA, Yasutomo; ITAMI, Kenichiro

2E5-18
Iridium-Catalyzed [2+2+2] Cycloaddition of Biaryl- and Heterobiaryl-Linked Diynes (Coll. Sci. Eng., Aoyama Gakuin Univ.) HASHIMOTO, Toru; º HARA, Tomohiro; FUJISAWA, Shunsuke; IZAWA, Mao; TAKEUCHI, Ryo

2E5-19 Young Scholar Lectures of CSJ
Radical Functionalization of Olefins by Photoredox Catalysis (Chem. Res. Lab., Tokyo Tech) º KOIKE, Takashi


Friday, March 27, PM

Chair: KUSUMOTO, Shuhei (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(2E5-29, 2E5-30, 2E5-31, 2E5-32, 2E5-33, 2E5-34)

2E5-29
Functionalization of Methylalkoxysilanes via Iridium-Catalyzed Chemoselective C(sp3)-H Borylation of the Methyl Group on Silicon (Grad. Sch. Eng., Kyoto Univ.) OHMURA, Toshimichi; º SASAKI, Ikuo; TORIGOE, Takeru; SUGINOME, Michinori

2E5-30
Highly-Efficient Ir/t-BuOK Catalyst for Non-Directed C(sp3)-H Borylation (Grad. Sch. Eng., Kyoto Univ.) OHMURA, Toshimichi; º TORIGOE, Takeru; SUGINOME, Michinori

2E5-31
Decarbonylation Reaction of Aliphatic Carboxylic Acid Using Cativa Catalyst System (Grad. Sch. Sci., Osaka Pref. Univ.) FUKUYAMA, Takahide; º KANEKO, Masaya; RYU, Ilhyong


Rh

2E5-32
Rhodium-Catalyzed Synthesis of Sila[n]helicene Derivatives via the Dehydrogenative Silylation of C(sp2)-H Bonds (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º OKADA, Ryo; MURAI, Masahito; TAKAI, Kazuhiko

2E5-33
Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation of C(sp3)-H Bonds (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º MORITA, Haruka; TAKESHIMA, Hirotaka; KUNINOBU, Yoichiro; MURAI, Masahito; TAKAI, Kazuhiko

2E5-34
Enantioselective Synthesis of Aminoindane carboxylic acid derivatives by the Catalytic [2+2+2] Cycloaddition (Sch. Advanced Sci. Eng., Waseda Univ.) º OBINATA, Shuhei; TAHARA, Yu-ki; SHIBATA, Takanori


Chair: FUCHIBE, Kohei (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(2E5-36, 2E5-37, 2E5-38, 2E5-39, 2E5-40, 2E5-41)

2E5-36
Catalytic trans-Hydroboration of Heteroaromatic Terminal Alkynes (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.) º KOBAYASHI, Hikaru; YAMAMOTO, Yasunori

2E5-37
Intermolecular Alkyne Cyclotrimerization Route to a Functionalized Cycloparaphenylene (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST; Grad. Sch. Sci., Eng., Tokyo Tech; ACT-C, JST) º MIYAUCHI, Yuta; ITO, Hideto; ITAMI, Kenichiro; TANAKA, Ken

2E5-38
Enantioselective Synthesis of the Planar-Chiral Benzosiloloferrocenes by Rh-Catalyzed Intramolecular C-H silylation (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º SHIZUNO, Tsubasa; SASAKI, Tomoya; SHIBATA, Takanori

2E5-39
Rh-Catalyzed Synthesis of Perinaphthenone Derivatives from 1-Naphthoic Acids and Internal Acetylenes (Grad. Sch. Sci., Osaka Pref. Univ.) HUKYAMA, Takahide; º SUGIMORI, Taiki; RYU, Ilhyong

2E5-40
Synthesis of Benzoxasilole Derivatives by Rhodium-Catalyzed [2+2+2] Cycloaddition (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º OBATA, Ryosuke; MURAYAMA, Koichi; TANAKA, Ken

2E5-41
Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition of 1,6-Enynes with Cyclopropylidenacetamides (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º NAKAMURA, Yu; YOSHIDA, Tomoka; MASUTOMI, Koji; TANAKA, Ken


Chair: ITO, Hideto (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(2E5-43, 2E5-45, 2E5-46, 2E5-47, 2E5-48)

2E5-43*
Mechanistic Study of Rhodium-Catalyzed Caboxylation of Simple Aromatic Compounds with Carbon Dioxide (Grad. Sch. Sci., Eng., Tokyo Tech) º SUGA, Takuya; TAKAYA, Jun; IWASAWA, Nobuharu

2E5-45
Double Annulation of Anilides with Two Alkynoates Catalyzed by an Electron-Deficient Rhodium(III) Catalyst (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º FUKUI, Miho; HOSHINO, Yuki; TANAKA, Ken

2E5-46
Oxidative Annulation of Bezoic Acids with Alkynes Catalized by an Electron-Deficient Rhodium(III) Catalyst (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º YAMAZAKI, Mutsumi; FUKUI, Miho; MIYAUCHI, Yuta; TANAKA, Ken

2E5-47
Rhodium-Catalyzed Cross-Dimerization and Trimerization of Allenes with Alkynes (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º SAKASHITA, Kazuki; TANAKA, Ken

2E5-48
Rhodium-catalyzed asymmetric addition of cyclopropylboroxine to aldimines. (Grad. Sch. Sci., Kyoto Univ.) º NAGAI, Tomotaka; TAKECHI, Ryosuke; EBE, Yusuke; NISHIMURA, Takahiro


Y, Sc, Yb

Chair: SEGAWA, Yasutomo (17:10-18:00)

* 17:00-17:10: interval for laptop PC connection.(2E5-50, 2E5-52, 2E5-53, 2E5-54)

2E5-50*
Aminoalkylation Reaction of Pyridine Derivatives through C-H Bond Activation by Group 3 Metal Amido Complexes (Grad. Sch. Eng. Sci., Osaka Univ.) º NAGAE, Haruki; SHIBATA, Yu; TSURUGI, Hayato; MASHIMA, Kazushi

2E5-52
Direct Allylation of Benzylic Alcohols with Allylsilanes Catalyzed by Sc(OTf)3 (Grad. Sch. Eng., Kyoto Univ.; Kyoto Univ. C-PiER; ICR, Kyoto Univ.) KONDO, Teruyuki; º DI, Yuanjun; KIMURA, Yu; TOSHIMITSU, Akio

2E5-53
Synthesis of Benzimidazoles and Benzothiazoles by Rare Earth Metal Catalyzed Condensation of 1,2-Diaminobenzene and 2-Aminobenzenethiol with Ketones (Kyoto Univ. C-PiER; Grad. Sch. Eng., Kyoto Univ.; ICR, Kyoto Univ.) KONDO, Teruyuki; º NAITO, Shunichi; YOSHIMURA, Tsutomu; KIMURA, Yu; TOSHIMITSU, Akio

2E5-54
Synthesis of 4(3H)-Quinazolinones by Yb(OTf)3-Catalyzed Condensation of 2-Aminobenzamides with 1,3-Dicarbonyl Compounds (Grad. Sch. Eng., Kyoto Univ.; Kyoto Univ. C-PiER; ICR, Kyoto Univ.) º YOSHIMURA, Tsutomu; KIMURA, Yu; TOSHIMITSU, Akio; KONDO, Teruyuki


Saturday, March 28, AM


Ir

Chair: NAKAJIMA, Kazunari (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(3E5-05, 3E5-06, 3E5-07, 3E5-08, 3E5-09)

3E5-05
Iridium-Catalyzed Hydroarylation of Vinyl Ethers via C-H Bond Activation (Grad. Sch. Sci., Kyoto Univ.) º EBE, Yusuke; NISHIMURA, Takahiro

3E5-06
Iridium-Catalyzed Asymmetric Intramolecular Hydrocarboxylation and Hydroimidation of Alkenes (Grad. Sch. Sci., Kyoto Univ.) º NAGAMOTO, Midori; NISHIMURA, Takahiro

3E5-07
Iridium-Catalyzed Regioselective Vinylic C-H Borylation of 2-Cycloalkene-1-one Derivatives. (Sch. Eng., Hokkaido Univ.) º ENDOH, Shun; SASAKI, Ikuo; ITO, Hajime; ISHIYAMA, Tatsuo

3E5-08
Iridium-Catalyzed Regioselective C-H Borylation of Heteroaromatic Aldimines Derived from Pentafluoroaniline (Sch. Eng., Hokkaido Univ.) º IKEDA, Toshiki; AMOU, Tatsunosuke; SASAKI, Ikuo; ITO, Hajime; ISHIYAMA, Tatsuo

3E5-09
Iridium-Catalyzed Vinylic C-H Borylation of Acyclic α,β-Unsaturated Carbonyl Compounds with Bis(pinacolato)diboron (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.) º TAGUCHI, Jumpei; SASAKI, Ikuo; DOI, Hana; ITO, Hajime; ISHIYAMA, Tatsuo


Chair: NISHIMURA, Takahiro (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(3E5-11, 3E5-12, 3E5-13, 3E5-14, 3E5-15)

3E5-11
Ir(I)-Catalyzed Enantioselective Intramolecular C-H Alkylation of Indoles at 2-Position (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º RYU, Naoto; TAKANO, Hideaki; SHIBATA, Takanori

3E5-12
Iridium-Catalyzed Benzylic C-H Bond Silylation of 4-Methylpyridines with Hydrosilanes (Grad. Sch. Eng., Osaka Univ.) FUKUMOTO, Yoshiya; º HIRANO, Masaya; CHATANI, Naoto

3E5-13
Visible Light-Mediated Aromatic Substitution Reactions via Successive Carbon-Carbon Bond Cleavage of Dihydropyridines and Cyanoarenes (The University of Tokyo Institute of Engineering Innovation, School of Engineering) º NOJIMA, Sunao; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki


Rh

3E5-14
Pyrazole as a Removable Directing Group in Rhodium-Catalyzed Carboxylation of Alkenyl C-H Bonds with CO2 (Sch. Sci., Tokyo Tech) º SAITOU, Takanobu; MIYAMA, Ko; TAKAYA, Jun; IWASAWA, Nobuharu

3E5-15
Synthesis of Planar-Chiral Cyclopentadienyl-Rhodium Complex and Catalytic Application (Grad. Sch. Sci., Osaka Univ.) º KANBAYASHI, Naoaya; OKAMURA, Taka-aki; ONITSUKA, Kiyotaka


Chair: SHIBATA, Takanori (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(3E5-17, 3E5-18, 3E5-19)

3E5-17
Synthesis and Application of Cyclopentadienyl Ligand Bearing a Permethylated Cyclodextrin (Grad. Sch. Eng., Osaka Univ.; Osaka Dent. Univ.) º YAMAUCHI, Hiroki; TSUDA, Susumu; IWASAKI, Takanori; FUJIWARA, Shin-ichi; KUNIYASU, Hitoshi; KAMBE, Nobuaki

3E5-18
Stereoselective Cyclization via C-H Bond Activation α to Nitrogen with a Rhodium Catalyst and Triazoles (Grad. Sch. Biosci. Biotech., Tokyo Tech) SENOO, Masato; º FURUKAWA, Ayana; HATA, Takeshi; URABE, Hirokazu

3E5-19 CSJ Award for Young Chemists
Studies on Transformations of C-C and C-H Bonds Utilizing Light as the Driving Force (Grad. Sch. Eng., Kyoto Univ.) º ISHIDA, Naoki


Saturday, March 28, PM

Chair: TAKAYA, Jun (13:40-14:30)

* 13:30-13:40: interval for laptop PC connection.(3E5-29, 3E5-30, 3E5-31, 3E5-32, 3E5-33)

3E5-29
Preparation of Tetrahydrofurans via C-H Bond Activation α to Oxygen with a Rh Catalyst and Triazoles (Grad. Sch. Biosci. Biotech., Tokyo Tech) SENOO, Masato; FURUKAWA, Ayana; º WATABE, Kaori; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

3E5-30
Rhodium-Catalyzed Transformation Reactions of Isoxazoles Involving N-O Bond Cleavage (Grad. Sch. Eng., Kyoto Univ.) OKAMOTO, Kazuhiro; º NANYA, Atsushi; OHE, Kouichi

3E5-31
One-Pot Synthesis of Substituted Thiazoles Starting from Terminal alkynes (Sch. Eng., Kyoto Univ.) º NAKAHASHI, Junki; FUNAKOSHI, Yuuta; FUJIMOTO, Yoshikazu; NAKAMURO, Takayuki; MIURA, Tomoya; MURAKAMI, Masahiro

3E5-32
Synthesis of Sulfur-Containing Medium-Membered Lactams by Rhodium-Catalyzed Reaction of Triazoles with Thiolactones (Grad. Sch. Eng., Kyoto Univ.) º FUJIMOTO, Yoshikazu; FUNAKOSHI, Yuuta; MIURA, Tomoya; MURAKAMI, Masahiro

3E5-33
Asymmetric Synthesis of Imino-substituted Spiropentanes and Their Thermal Skeletal Rearrangemetnt Constructing trans-Cycloalkene Structures (Grad. Sch. Eng., Kyoto Univ.) º NAKAMURO, Takayuki; LIANG, Chia-jung; MIURA, Tomoya; MURAKAMI, Masahiro


Sunday, March 29, AM


Ti, Ni

Chair: OOHASHI, Masato (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(4E5-05, 4E5-07, 4E5-08, 4E5-09)

4E5-05*
Halogen Exchange Reaction of Aliphatic Fluorine Compounds with Organic Halides as Halogen Source (CRC, Hokkaido Univ.) º MIZUKAMI, Yuki; SONG, Zhiyi; TAKAHASHI, Tamotsu

4E5-07
Reactions of Unsaturated Titanium Carbene Complexes with Vinylboranes and Vinylsilanes (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) TAKEDA, Takeshi; º TERAMOTO, Yuzo; INOUE, Yuta; TSUBOUCHI, Akira

4E5-08
Synthesis of highly π-conjugated porphyrin metal complexes under mild conditions (Fac. Eng., Utsunomiya Univ.) º ISHII, Yutaro; OBA, Toru; ITO, Satoshi

4E5-09
Nickel-Catalyzed Doublecarboxylation of Alkynes Employing Carbon Dioxide (Grad. Sch. Eng., Kyoto Univ.; FIFC, Kyoto Univ.) º TANI, Yosuke; HORIMOTO, Yuichiro; MIZOE, Taiga; SAYYED, Bahsha Fareed; FUJIHARA, Tetsuaki; TERAO, Jun; SAKAKI, Shigeyoshi; TSUJI, Yasushi


Ni, Zn

Chair: FUJIHARA, Tetsuaki (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(4E5-11, 4E5-12, 4E5-13, 4E5-14)

4E5-11
Development of Multifold Cross-linked Polystyrene Bisphosphine Hybrids and Its Application to Nickel-catalyzed Cross-coupling Reactions (Fac. Sci., Hokkaido Univ.) º HARADA, Tomoya; IWAI, Tomohiro; SAWAMURA, Masaya

4E5-12
Nickel-Catalyzed Fluoroarene Synthesis via α-Fluorine Elimination and Its Mechanism (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º WATABE, Yota; ICHITSUKA, Tomohiro; FUJITA, Takeshi; ICHIKAWA, Junji

4E5-13
Nickel-Catalyzed Stannylation of Aryl Halides (Grad. Sch. Eng., Hiroshima Univ.) º ASAKURA, Ryota; KOMEYAMA, Kimihiro; TAKAKI, Ken

4E5-14*
Preparation of 1,3-dizinc from bis(iodozincio)methane and allenones. (Grad. Sch. Eng., Kyoto Univ.) º HARAGUCHI, Ryosuke; MATSUBARA, Seijiro


Zn

Chair: IWAI, Tomohiro (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(4E5-17, 4E5-18, 4E5-19, 4E5-21)

4E5-17
Isolation and Structural Characterization of gem-Bis(iodozincio)methane Complexes Stabilized with Nitrogen Ligands (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º HOSOKAWA, Naoki; NISHIDA, Yusuke; MURAI, Masahito; TAKAI, Kazuhiko

4E5-18
Regioselective Addition of Benzylzinc Reagents to Pyridines at Their 4-Position (Grad. Sch. Biosci. Biotech., Tokyo Tech) MIZUMORI, Tomoya; º MITSUI, Takahiro; MIYANAKA, Kento; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

4E5-19*
Synthesis of Trifluorovinyl Zinc Compound from Tetrafluoroethylene (Grad. Sch. Eng., Osaka Univ.) º KIKUSHIMA, Kotaro; OHASHI, Masato; OGOSHI, Sensuke

4E5-21
Selective Synthesis of Indole Derivatives via a Dimetallic Intermediate (Grad. Sch. Sci., The Univ. of Tokyo) º ISOMURA, Mayuko; YAMAUCHI, Shinichi; ILIES, Laurean; NAKAMURA, Masaharu; NAKAMURA, Eiichi

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