The 95th Annual Meeting of The Chemical Society of Japan

Date: March 26th - 29th, 2015

Venue: Funabashi Campus, College of Science and Technology, Nihon University / School of Pharmacy, Nihon University, Chiba, Japan

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Room E4

Bldg.10 1041


[Organic Chemistry -Reaction and Synthesis- Organometallic Compounds]


Thursday, March 26, AM


Pd

Chair: SHIBAHARA, Fumitoshi (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(1E4-05, 1E4-06, 1E4-07, 1E4-08, 1E4-09)

1E4-05
The Pd(OAc)2-Catalyzed Lactonization of Aromatic Acetamides Involving Oxidation of the ortho C-H Bonds (Grad. Sch. Eng., Osaka Univ.) º IGARASHI, Takuya; NOGUCHI, Moe; UEMURA, Takeshi; CHATANI, Naoto

1E4-06
Palladium-Catalyzed Synthesis of Dibenzothiophenes via the Carbon-Sulfur Bond Cleavage (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º MASUYA, Yoshihiro; BABA, Katsuaki; CHATANI, Naoto

1E4-07
Palladium-Catalyzed Synthesis of Phosphole Derivatives through Double Carbon-Phosphorus Bond Cleavage (Grad. Sch. Eng., Osaka Univ.) º BABA, Katsuaki; TOBISU, Mamoru; CHATANI, Naoto

1E4-08
Base-Free Palladium-Catalyzed Borylation of Aryl Chlorides (Grad. Sch. Sci., Kyoto Univ.; Grad. Sch. Sci., Osaka Pref. Univ.) º YAMAMOTO, Yutaro; MATSUBARA, Hiroshi; YORIMITSU, Hideki; OSUKA, Atsuhiro

1E4-09
Programmed Synthesis of Multiply Arylated Arenes (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST) º SUZUKI, Shin; SEGAWA, Yasutomo; YAMAGUCHI, Junichiro; ITAMI, Kenichiro


Chair: TOBISU, Mamoru (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(1E4-11, 1E4-12, 1E4-13, 1E4-14, 1E4-15)

1E4-11
Synthesis of Heteroaryl-Substituted Allenes by Palladium-Catalyzed Cross-Coupling of Propargyl Esters with Heteroaromatic Zinc Reagents (Coll. Sci. Eng., Aoyama Gakuin Univ.) HASHIMOTO, Toru; TOMITA, Naoki; º TSUYUKI, Ami; TAKEUCHI, Ryo

1E4-12
Development of a Highly Active Pd/Cu Bimetallic Catalyst for Suzuki-Miyaura Reactions (Fac. Eng., Niigata Univ.; Grad. Sch. Sci. and Technol., Niigata Univ.) HOSHI, Takashi; º SHISHIDO, Yuka; SUZUKI, Toshio; HAGIWARA, Hisahiro

1E4-13
Palladium-Catalyzed Efficient Electrophilic Allylation of Amine with Allyl Alcohol by Using Phosphine-Borane Ligand. (Grad. Sch. Eng., Nagasaki Univ.) º KUMAGAE, Hidenobu; HIRATA, Goki; ONODERA, Gen; KIMURA, Masanari

1E4-14
Synthesis of Nitrogen-Containing Heterocyclic Compounds via Oxidation of Alcohols Catalyzed by Palladium Complex (Grad. Sch. Eng., Nagasaki Univ.) º ISHII, Chihiro; MORI, Takamichi; MUKAI, Asuka; ONODERA, Gen; KIMURA, Masanari

1E4-15
C-H bond selective direct arylation of 2-bromo-N-methylimidazole (Fac. Eng., Gifu Univ.) º YOKOE, Yuma; YAMAUCHI, Takayuki; SHIBAHARA, Fumitoshi; MURAI, Toshiaki


Chair: YORIMITSU, Hideki (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(1E4-17, 1E4-19, 1E4-21)

1E4-17*
Copolymerization of Propylene and Polar Monomers by Palladium/Imidazoquinolinolate Catalysts (Grad. Sch. Eng., The Univ. of Tokyo) º NAKANO, Ryo; NOZAKI, Kyoko

1E4-19*
Palladium-Catalyzed C(sp2)-C(sp3) Coupling Reaction between Arenes and Oxiranes via C-H Bond Activation (The Univ. of Tokyo ERATO-JST) º WANG, Zhen; KUNINOBU, Yoichiro; KANAI, Motomu

1E4-21
Allylic Arylation Reaction with a Highly Active NNC-Pincer Palladium Complex Catalyst (IMS; Sch. Physical Sci., SOKENDAI) º HAMASAKA, Go; SAKURAI, Fumie; UOZUMI, Yasuhiro


Thursday, March 26, PM

Chair: IWASAWA, Nobuharu (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(1E4-29)

1E4-29 CSJ Award for Creative Works
Carbon-Fluorine Bond Activation by Using the Properties of Fluorine Substituent (Univ. of Tsukuba Division of Chemistry, Faculty of Pure and Applied Sciences) º ICHIKAWA, Junji


Chair: KUNIYASU, Hitoshi (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(1E4-36, 1E4-38, 1E4-40)

1E4-36*
The Concise Synthesis of Unsymmetric Triarylacetonitriles via Pd-Catalyzed Sequential Arylation (WPI-ITbM, Nagoya Univ.) º NAMBO, Masakazu; YAR, Muhammad; SMITH, Joel D.; CRUDDEN, Cathleen M.

1E4-38*
Ethylene/polar monomer copolymerization by bisphosphinemonoxide-palladium complexes: Effect of substituents and mechanistic investigation (Grad. Sch. Eng., The Univ. of Tokyo) º MITSUSHIGE, Yusuke; CARROW, Brad P.; ITO, Shingo; NOZAKI, Kyoko

1E4-40*
Palladium-catalyzed direct arylation of thiocarbonylated heteroarenes (Fac. Eng., Gifu Univ.) º YAMAUCHI, Takayuki; SHIBAHARA, Fumitoshi; MURAI, Toshiaki


Cu

Chair: OSAKO, Takao (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(1E4-43, 1E4-44, 1E4-45, 1E4-46, 1E4-47, 1E4-48)

1E4-43
Regioselective [3+2] cyclization as a key reaction for the synthesis of asymmetric aryl furans (Grad. Sch. Sci. Eng., Yamaguchi Univ.) º ISHIKAWA, Shingo; NODA, Yushi; FUJIMOTO, Ryo; NISHIKATA, Takashi

1E4-44
Copper-Catalyzed Formal Allylic C-H Carboxylation with Carbon Dioxide through Deprotonative Alumination (RIKEN CSRS) º UENO, Atsushi; TAKIMOTO, Masanori; HOU, Zhaomin

1E4-45
Highly Regioselective Alkylative Carboxylation of Allenamide with CO2 and Dialkylzinc Reagents Catalyzed by NHC-Copper Complex (Grad. Sch. Sci., Eng., Saitama Univ.; RIKEN Organometallic Chemistry Laboratory; RIKEN CSRS) º GHOLAP, Sandeep Suryabhan; TAKIMOTO, Masanori; HOU, Zhaomin

1E4-46
Cu-catalyzed Perfluoroarylation of 1,3-Butadiene (Grad. Sch. Eng., Osaka Univ.) º OKAMOTO, Kanako; IWASAKI, Takanori; KUNIYASU, Hitoshi; KAMBE, Nobuaki

1E4-47
Copper catalyzed Z-selective alkylation of styrenes (Grad. Sch. Sci. Eng., Yamaguchi Univ.) º NAKAMURA, Kimiaki; INOUE, Yuki; ISHIKAWA, Shingo; NISHIKATA, Takashi

1E4-48
Judicious choice of amines enables switching reaction pathways of carboamidation and olefination with haloamides catalyzed by a copper salt (Grad. Sch. Sci. Eng., Yamaguchi Univ.) º ITONAGA, Kohei; YAMAGUCHI, Norihiro; ISHIKAWA, Shingo; NISHIKATA, Takashi


Chair: IWASAKI, Takanori (17:10-18:00)

* 17:00-17:10: interval for laptop PC connection.(1E4-50, 1E4-51, 1E4-52, 1E4-53, 1E4-54)

1E4-50
Copper catalyzed [2+1] and [3+2] cycloaddition reactions of 2-bromocarbonyl compounds and styrenes (Grad. Sch. Sci. Eng., Yamaguchi Univ.) º NODA, Yushi; FUJIMOTO, Ryo; WADA, Masaru; ISHIKAWA, Shingo; NISHIKATA, Takashi

1E4-51
Construction of Chiral All-Carbon Quaternary Stereocentres Based on Enantioselective Propargylic Substitution Reaction of Propargylic Esters with Indoles (Grad. Sch. Eng., The Univ. of Tokyo) º TSUCHIDA, Kohei; SENDA, Yasushi; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

1E4-52
Grignard/Ce/Cu Trimetallic Reagent-mediated Preparation of Nitrones from Nitro Compounds (Grad. Sch. Biosci. Biotech., Tokyo Tech) TATSUMI, Yuta; º TANAKA, Naomi; HATA, Takeshi; URABE, Hirokazu

1E4-53
Cu/Phosphoramidite-Catalyzed Asymmetric Insertion of Carbenoids into Alkyne C-H Bonds (IMS Department of Life and Coordination-Complex Molecular Scienc) º NAGAOSA, Makoto; OSAKO, Takao; UOZUMI, Yasuhiro

1E4-54
Synthesis of Fluorine-Substituted Five-Membered Silyl Enol Ethers via Cu-Catalyzed Introduction of Difluoromethylene Group (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º HU, Ji; FUCHIBE, Kohei; ICHIKAWA, Junji


Friday, March 27, AM


Pt

Chair: AIKAWA, Kohsuke (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(2E4-05, 2E4-06, 2E4-07, 2E4-08, 2E4-09)

2E4-05
Platinum-Catalyzed Alkenylation of Acetals with Alkenylsilanes (Grad. Sch. Sci., Eng., Saitama Univ.) º FUKUDA, Daiki; KINOSHITA, Hidenori; MIURA, Katsukiyo

2E4-06
Development of Catalytic Reactions Using Zwitterionic Platinum (II) Complexes Prepared from Alkyne-containing Bisphosphine Ligands (Grad. Sch. Eng., Kyoto Univ.) OKAMOTO, Kazuhiro; º FUNASAKA, Satoshi; OHE, Kouichi


Au

2E4-07
Gold-Catalyzed Skeletal Rearrangement of O-Propargylic Formaldoximes via Intermolecular Methylene Group Transfer (Grad. Sch. Sci., Tohoku Univ.) º GIMA, Shinya; NAKAMURA, Itaru; TERADA, Masahiro

2E4-08
Au25(PET)18 catalyzed reaction of Aldehyde, Amine, and Alkyne (Fac. Chem. Materials and Bioeng., Kansai Univ.) º ADACHI, Yurina; KAWASAKI, Hideya; OBORA, Yasushi

2E4-09
Catalytic Asymmetric Dearomatization of 1-Aminonaphthalene Derivatives Using Electron-Rich Heterocycles as Nucleophiles (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º BABA, Takafumi; OKA, Junko; TANAKA, Ken


Chair: OKAMOTO, Kazuhiro (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(2E4-11, 2E4-12, 2E4-13, 2E4-14, 2E4-15)

2E4-11
Catalytic asymmetric [4+2] cycloaddition reaction using chiral Au complexes and its mechanistic analysis (Grad. Sch. Sci., Eng., Tokyo Tech) º NANKO, Masaki; AIKAWA, Kohsuke; ITO, Shigekazu; MIKAMI, Koichi

2E4-12
Development of catalytic asymmetric reactions by Au complex bearing novel chirally flexible diphosphine ligands (Grad. Sch. Sci., Eng., Tokyo Tech) º MISHIMA, Katsuyuki; AIKAWA, Kohsuke; ITO, Shigekazu; MIKAMI, Koichi


Ag

2E4-13
Chiral Ag(I) Complex-Catalyzed Asymmetric 1,4-Conjugate Addition of Pyrroline Ester to Nitroalkene (Fac. Sci. Eng., Chuo Univ.) º KOIZUMI, Akihiro; KIMURA, Midori; ARAI, Yuri; TOKORO, Yuichiro; FUKUZAWA, Shin-ichi

2E4-14
Silver-Catalyzed Sequential Allylation Reaction via Vinylcarbenoid Intermediate from Cyclopropenes (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º NAKANO, Takeo; ENDOU, Kouhei; UKAJI, Yutaka


Cu

2E4-15
Copper-mediated Transfer Annulation for Construction of 5,10-Dihydroindolo[3,2-b]indoles (WPI-AIMR, Tohoku Univ.) º HO, Hon Eong; ASAO, Naoki; YAMAMOTO, Yoshinori; JIN, Tienan


Chair: ITO, Shigekazu (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(2E4-17, 2E4-19, 2E4-20)

2E4-17*
Enantioposition-Selective Copper-Catalyzed Azide-Alkyne Cycloaddition (IMS) º OSAKO, Takao; UOZUMI, Yasuhiro

2E4-19
Copper(I)-Catalyzed Regio- and Enantioselective Borylative Dearomatization of Indoles (Sch. Eng., Hokkaido Univ.) º HAYAMA, Keiichi; KUBOTA, Koji; YAMAMOTO, Eiji; ITO, Hajime

2E4-20*
Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.) º KUBOTA, Koji; YAMAMOTO, Eiji; ITO, Hajime


Friday, March 27, PM

Chair: ITO, Hajime (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(2E4-29, 2E4-32, 2E4-33, 2E4-34)

2E4-29 CSJ Award for Young Chemists
Neighboring Electrophilic Activation of Active Center for Development of Catalytic Reactions via Organometallic Intermediates (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º ENDOU, Kouhei

2E4-32
Synthesis of N-Heterocycles by Copper-Catalyzed Intramolecular C-H/N-H Coupling (Grad. Sch. Eng., Osaka Univ.) º TAKAMATSU, Kazutaka; HIRANO, Koji; SATOH, Tetsuya; MIURA, Masahiro

2E4-33
Acridine Synthesis via Copper-Mediated Dehydrogenative Cyclization of Tritylamines (Osaka Univ. Graduate School of Engineering) º MORIOKA, Ryosuke; HIRANO, Koji; SATOH, Tetsuya; MIURA, Masahiro

2E4-34
Development of Electrophilic Amination using N-Methoxyamines toward a Multistep Synthesis (Fac. Sci. Tech., Keio Univ.) º FUKAMI, Yutaro; MEGURO, Tatsuhiko; WADA, Takamasa; SATO, Takaaki; CHIDA, Noritaka


Chair: HIRANO, Koji (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(2E4-36, 2E4-37, 2E4-38, 2E4-39, 2E4-40, 2E4-41)

2E4-36
Copper-catalyzed Odorless Thiolation of Aryl Boronic Acids using Thiosulfonates (IBB, Tokyo Med. and Dental Univ.; Tokyo Med. and Dental Univ. Med. Res. Inst.) º SUGIMURA, Yasuyuki; YOSHIDA, Suguru; SHIMIZU, Shigeomi; HOSOYA, Takamitsu

2E4-37
Protection and Deprotection Methods of Strained Alkynes and Application to the Synthesis of Functionalized Cycloalkynes (IBB, Tokyo Med. and Dental Univ.; Grad. Sch. Sci., Eng., Tokyo Tech) º HATAKEYAMA, Yasutomo; YOSHIDA, Suguru; JOHMOTO, Kohei; UEKUSA, Hidehiro; HOSOYA, Takamitsu

2E4-38
Catalytic C-H imidation of aromatic core of functional molecules(1) (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST) º MURAKAMI, Kei; KAWAKAMI, Takahiro; ITAMI, Kenichiro

2E4-39
Catalytic C-H imidation of aromatic core of functional molecules(2) (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST) º KAWAKAMI, Takahiro; MURAKAMI, Kei; ITAMI, Kenichiro

2E4-40
N-arylation reaction Catalyzed by DMF-protected Copper Nanoparticles (Fac. Chem. Materials and Bioeng., Kansai Univ.) º KITAI, Katsuya; OBORA, Yasushi

2E4-41
Rapid Sythesis of Sialic Acid Derivatives via Ligand-Controlled, Stereodivergent Propagylation of Unprotected Aldoses (Grad. Sch. Pharm., The Univ. of Tokyo) º WEI, Xiaofeng; SHIMIZU, Yohei; KANAI, Motomu


Pd

Chair: MURAKAMI, Kei (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(2E4-43, 2E4-45, 2E4-46, 2E4-47, 2E4-48)

2E4-43*
Enantioselective Synthesis of α-Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation (Caltech Divison of Chemistry & Chemical Engineering) º NUMAJIRI, Yoshitaka; PRITCHETT P, Beau; CHIYODA, Koji; STOLTZ M, Brian

2E4-45
Palladium-Catalyzed Cross-Coupling Reaction of Diarylmethyl Carbonates and Terminal Alkynes (Grad. Sch. Eng., Osaka Univ.) º TABUCHI, Sho; HIRANO, Koji; SATOH, Tetsuya; MIURA, Masahiro

2E4-46
Preparation of Arenylmethylzinc Reagent from Iodoarene by Pd/Ni-Catalyzed Cross-Coupling Reaction (Sch. Eng., Kyoto Univ.) º SHIMADA, Yukako; MATSUBARA, Seijiro

2E4-47
The oxidative addition of fluorinated alkenyl chlorides to palladium(0) complexes and its catalytic application to Suzuki-Miyaura coupling (Sagami Chemical Research Institute) º MIZUNO, Masataka; YAMAMOTO, Tetsuya; YAMAKAWA, Tetsu

2E4-48
NHC-palladacycle catalyzed addition of arylboronic acid derivatives to carbonyl compounds (Sagami Chemical Research Institute) º ANJO, Kaori; YAMAMOTO, Tetsuya; YAMAKAWA, Tetsu


Chair: ASANO, Keisuke (17:10-18:10)

* 17:00-17:10: interval for laptop PC connection.(2E4-50, 2E4-51, 2E4-52, 2E4-53, 2E4-54, 2E4-55)

2E4-50
Pd-catalyzed addition reaction of aromatic thioester to norbornene derivatives (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º TANII, Saori; YAMAGUCHI, Masahiko

2E4-51
Synthesis of 1,4-dithiin derivatives using rhodium-cataylzed sulfur addition reaction to cycloalkynes (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º ICHIKAWA, Takuya; YAMAGUCHI, Masahiko

2E4-52
Rhodium-catalyzed Aryl Exchange Reaction of Pentaphenylcyclopentaphosphine and Aryl Sulfides (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º TAKAHASHI, Kazuya; YAMAGUCHI, Masahiko

2E4-53
Development of novel catalytic enantioselective 1,2-addition reactions of acetylene compounds and fluoromethylpyruvate (Grad. Sch. Sci., Eng., Tokyo Tech) º KONDO, Daisuke; YOSHIDA, Seiya; HONDA, Kazuya; AIKAWA, Kohsuke; MIKAMI, Koichi

2E4-54
Development of chiral Pd-catalyzed enantioselective 1,3-dipolar cycloaddition of ynone dipolarophiles (Grad. Sch. Sci., Eng., Tokyo Tech) º HONDA, Kazuya; AIKAWA, Kohsuke; MIKAMI, Koichi

2E4-55
Palladium-Catalyzed Annulation of Alkynyl Ferrocenyl Ethers with Internal Alkynes via C-H Bond Activation (Grad. Sch. Sci. Eng., Chuo Univ.) º MITSUI, Takashi; TOKORO, Yuichiro; HIYAMA, Tamejiro; FUKUZAWA, Shin-ichi


Saturday, March 28, AM


Cu

Chair: TAKAYA, Jun (09:10-10:10)

* 9:00-9:10: interval for laptop PC connection.(3E4-02, 3E4-03, 3E4-04, 3E4-05, 3E4-06, 3E4-07)

3E4-02
Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective direct allylic alkylation of heteroarenes (Fac. Sci., Hokkaido Univ.) º ZHANG, Heng; HARADA, Ayumi; OHMIYA, Hirohisa; SAWAMURA, Masaya

3E4-03
Copper(I)-catalyzed hydrogenation of alkynes with molecular hydrogen (Fac. Sci., Hokkaido Univ.) º TAKAMICHI, Wakamatsu; HIROHISA, Ohmiya; MASAYA, Sawamura

3E4-04
Copper-Catalyzed Semihydrogenation of Internal Alkynes (Grad. Sch. Eng., Kyoto Univ.; CREST, JST) º KAMEYAMA, Ryohei; SEMBA, Kazuhiko; NAKAO, Yoshiaki

3E4-05
Development of Catalytic Asymmetric Conjugate Addition of Organometallic Reagents to Conjugated Dienones Using Multinuclear Copper Catalysts (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º KOBAYASHI, Tomoki; ENDOU, Kouhei; UKAJI, Yutaka

3E4-06
Cu-catalyzed sp3 coupling reaction with 2-pyridylsulfonyl group (Tokyo Institute of Technology) º TOJO, Toshifumi; WADA, Kyohei; OGAWA, Narihito; KOBAYASHI, Yuichi

3E4-07
Copper-catalyzed Iodocyanation of Alkynes Using Cyanogen Iodide (Grad. Sch. Eng., Kyoto Univ.) º SAKATA, Naoki; OKAMOTO, Kazuhiro; OHE, Kouichi


Chair: OKAMOTO, Kazuhiro (10:20-11:20)

* 10:10-10:20: interval for laptop PC connection.(3E4-09, 3E4-10, 3E4-11, 3E4-12, 3E4-13, 3E4-14)

3E4-09
Copper-Catalyzed Coupling of Disulfides with Sodium Sulfinates (Sch. of Med., Fukushima Med. Univ.) º TANIGUCHI, Nobukazu


Pd

3E4-10
Synthesis of Unsymmetrical Diborons through PSiP-Pincer Palladium Complex Catalyzed Boron Exchange Reaction (Grad. Sch. Sci., Eng., Tokyo Tech) º MIURA, Norio; ITO, Tatsuyoshi; KIRAI, Naohiro; TAKAYA, Jun; IWASAWA, Nobuharu

3E4-11
Direct C-Allylation of 1,3,5-Trihydroxybenzene with Allyl Alcohol Activated by Palladium Catalyst and Triethylborane (Grad. Sch. Eng., Nagasaki Univ.) º MIYAHARA, Yuhei; HIRATA, Goki; ONODERA, Gen; KIMURA, Masanari

3E4-12
Arylboration of Alkynes by Cooperative Palladium/Copper Catalysis (Grad. Sch. Eng., Kyoto Univ.; CREST, JST) º SEMBA, Kazuhiko; YOSHIZAWA, Megumi; NAKAO, Yoshiaki

3E4-13
Hydrocarboxylation of Alkenes Catalyzed by PGeP-Pincer Type Palladium Complexes using Formate Salt as a Reductant and a CO2 Source (Grad. Sch. Sci., Eng., Tokyo Tech) º MIYAMA, Ko; TAKAYA, Jun; IWASAWA, Nobuharu

3E4-14
Mechanistic Study on Palladium/o-Chloranil-Catalyzed C-H Arylation of Polycyclic Aromatic Hydrocarbon (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST) º SHIBATA, Mari; ITO, Hideto; ITAMI, Kenichiro


Chair: SEMBA, Kazuhiko (11:30-12:30)

* 11:20-11:30: interval for laptop PC connection.(3E4-16, 3E4-17, 3E4-18, 3E4-19, 3E4-20, 3E4-21)

3E4-16
Palladium-catalyzed Direct C-H Arylation of Arenes with Aryl Sulfides (Grad. Sch. Sci., Kyoto Univ.) º OTSUKA, Shinya; YORIMITSU, Hideki; OSUKA, Atsuhiro

3E4-17
Palladium-catalyzed Direct Arylation of 2-Furaldehyde (Grad. Sch. Integrated Basic Sci., Nihon Univ.) º SATO, Shun; MINAKAWA, Maki; KAWATSURA, Motoi

3E4-18
Palladium-catalyzed Side Chain C(α) Allylic Alkylation of 2-Alkylpyridines (Fac. Sci., Hokkaido Univ.) º MURAKAMI, Ryo; IWAI, Tomohiro; SAWAMURA, Masaya

3E4-19
Phenathroline-palladium catalyzed olefin isomerization via chain walking. (Grad. Sch. Sci. Tech., Keio Univ.) º YAMASAKI, Yuya; KAKIUCHI, Fumitoshi; KOCHI, Takuya

3E4-20
Key mechanistic details of Palladium(II) catalyzed C-H functionalization/intramolecular C-S bond formation in thiobenzanilide: A GRRM/AFIR study (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.; Emory University Cherry L. Emerson Center for Scientific Computation) º UEMATSU, Ryohei; MAEDA, Satoshi; MUSAEV, Djamaladdin G.; TAKETSUGU, Tetsuya

3E4-21
Catalytic Asymmetric Synthesis of Axially Chiral Biaryls by the Enantioselective C-H Olefination (Grad. Sch. Sci., Osaka Pref. Univ.) º YASUDA, Rie; KAMIKAWA, Ken


Saturday, March 28, PM

Chair: OHMIYA, Hirohisa (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(3E4-29, 3E4-32, 3E4-33, 3E4-34)

3E4-29 Young Scholar Lectures of CSJ
New Trends in Enantioselective Reactions Promoted by a Pd(II) Catalyst (ISIR, Osaka Univ.) º TAKENAKA, Kazuhiro

3E4-32
Enantioselective synthesis of chiral spiro compounds and their applications to organocatalysis (ISIR, Osaka Univ.) º TAKEUCHI, Yoshiki; FAN, Lulu; TAKIZAWA, Shinobu; SASAI, Hiroaki

3E4-33
Terminal-selective introduction of oxygen functional group to terminal alkenes by palladium catalysts using H2O as nucleophilic agent (Fac. Sci., Kyushu Univ.) º MANTANI, Kohei; ISHIDA, Sayuri; TOMITA, Ren; ISHIDA, Tamao; HAMASAKI, Akiyuki; TOKUNAGA, Makoto

3E4-34
Divergent Synthesis of SPRIX Ligands Having Oxygen Functionalities (ISIR, Osaka Univ.) º LIN, Xianjin; TAKENAKA, Kazuhiro; SASAI, Hiroaki


Sunday, March 29, AM


Li

Chair: HORINO, Yoshikazu (09:40-10:40)

* 9:30-9:40: interval for laptop PC connection.(4E4-05, 4E4-07, 4E4-08, 4E4-09, 4E4-10)

4E4-05*
Substitution of Allylic Phosphates with Diarylmethyl Anions (Grad. Sch. Biosci. Biotech., Tokyo Tech) º KAWASHIMA, Hidehisa; SAEKI, Ryohei; OGAWA, Narihito; KOBAYASHI, Yuichi

4E4-07
Asymmetric Synthesis of Multi-substituted Triptycenes via Enantioselective Alkynylation of Dibromoanthraquinone (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º KAMIMURA, Yuri; SHIBATA, Takanori

4E4-08
Synthesis of a New Bulky Piperidine Analogue and Applications to Metal Amide Bases (Grad. Sch. Sci., Hiroshima Univ.) º MORISAKO, Shogo; YAMAMOTO, Yohsuke


Mg

4E4-09
Application of CPME as a solvent for Grignard reactions (OIT Graduate School of Engineering) º SHIBUKAWA, Keisuke; MASUYAMA, Araki; KOBAYASHI, Shoji


Pd

4E4-10
Palladium-Catalyzed Asymmetric Allylic Alkylation of Indoles Using Axially Chiral Ligands with Cinnamyl Group (Grad. Sch. Eng., Chiba Univ.) MINO, Takashi; º ASANO, Moeko; EBISAWA, Toshibumi; NISHIKAWA, Kenji; SAKAMOTO, Masami


Chair: MINAKAWA, Maki (10:50-11:40)

* 10:40-10:50: interval for laptop PC connection.(4E4-12, 4E4-13, 4E4-14, 4E4-15, 4E4-16)

4E4-12
Palladium-Catalyzed Three-Component Reaction of 3-(Tributylstannyl)ally Acetates, Aldehydes, and Organoboranes (Fac. Eng., Univ. of Toyama) º SUGATA, Miki; HORINO, Yoshikazu; ABE, Hitoshi

4E4-13
Palladium-Catalyzed Cross-Coupling of Acyl Halides with Organosilicon Compounds Leading to Diaryl Ketones (Grad. Sch. Fac. Sci. Technol., Tokyo Univ. of Sci.) º MAEGAWA, Yuki; OGIWARA, Yohei; SAKAI, Norio

4E4-14
Palladium-Catalyzed Silylative Ring-Opening of Alkenylepoxides with Hexamethyldisilane (Grad. Sch. Sci., Eng., Saitama Univ.) º OOTA, Kazuki; KINOSHITA, Hidenori; MIURA, Katsukiyo

4E4-15
Palladium-Catalyzed Multi-Component Reaction of 3-(Tributylstannyl)propargyl Acetates, Aldehydes, and Organoboranes (Fac. Eng., Univ. of Toyama) º AIMONO, Ataru; HORINO, Yoshikazu; ABE, Hitoshi

4E4-16
Pd/light-induced Radical Vinylation of Alkyl Iodides (Grad. Sch. Sci., Osaka Pref. Univ.) º SUMINO, Shuhei; RYU, Ilhyong


Chair: OGIWARA, Yohei (11:50-12:40)

* 11:40-11:50: interval for laptop PC connection.(4E4-18, 4E4-19, 4E4-20, 4E4-21, 4E4-22)

4E4-18
(Aminomethyl)silylboronic Ester: A Synthetic Equivalent of Silene under Palladium-Catalyzed Conditions (Grad. Sch. Eng., Kyoto Univ.) OHMURA, Toshimichi; º NISHIURA, Hiroki; SUGINOME, Michinori

4E4-19
Efficient Synthesis of 3-Aryloxindoles Utilizing [1,2]-Phospha-Brook Rearrangement and Palladium-Catalyzed Cross-Coupling Reaction (Grad. Sch. Sci., Tohoku Univ.) º TAKEI, Akira; KONDOH, Azusa; TERADA, Masahiro

4E4-20
Synthesis of Benzofuran derivatives by the palladium-catalyzed reaction of 2-haloallyl esters with phenols (Grad. Sch. Integrated Basic Sci., Nihon Univ.) º UDAGAWA, Takumi; WATANABE, Hirotaka; MINAKAWA, Maki; KAWATSURA, Motoi

4E4-21
Enantioselective Synthesis of Axially Chiral Biaryls Bearing an Ester Group via Asymmetric Suzuki-Miyaura Coupling Using Helically Chiral Polymer Ligand PQXphos (Grad. Sch. Eng., Kyoto Univ.) º AKAI, Yuto; KONNERT, Laure; YAMAMOTO, Takeshi; SUGINOME, Michinori

4E4-22
Palladium-catalyzed Intramolecular Alkene Insertion into Carbon-Nitrogen Bonds of β-Lactams (Grad. Sch. Eng., Kyoto Univ.) º OKAJIMA, Satoshi; YADA, Akira; MURAKAMI, Masahiro

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