The 95^th Annual Meeting of The Chemical Society of Japan

Room E2

Bldg.10 1032

[Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds]

Thursday, March 26, AM

Chair: OHMORI, Ken (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(1E2-01, 1E2-02, 1E2-03, 1E2-04, 1E2-06)

1E2-01
Desymmetrization of meso-1,4-Dioxane Derivatives Using Enantioselective Reductions (Grad. Sch. Eng., Mie Univ.) º SHINDO, Hiroaki; HACHIYA, Iwao; SHIMIZU, Makoto

1E2-02
Enantioseletive Synthesis of Planar Chiral Cyclic Amines based on the Catalytic Asymmetric Cyclization (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) º ANO, Yusuke; ICHIKAWA, Nobumasa; IGAWA, Kazunobu; TOMOOKA, Katsuhiko

1E2-03
Synthesis and Stereochemical Behavior of 9-membered Planar Chiral Diallylic Amine Derivatives having C4-Substituent (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) ANO, Yusuke; º HAYASHI, Junichi; UEHARA, Kazuhiro; IGAWA, Kazunobu; TOMOOKA, Katsuhiko

1E2-04^*
Site- and Enantioselective Oxidative Cycloamination Using Chiral Hypoiodite Catalysis (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º SUZUKI, Daisuke; UYANIK, Muhammet; ISHIHARA, Kazuaki

1E2-06
Chiral Hypoiodite-Catalyzed Enantioselective Oxidative Cyclization to Alicyclic Ethers (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º HAYASHI, Hiroki; UYANIK, Muhammet; ISHIHARA, Kazuaki

Chair: NAKA, Hiroshi (10:10-11:00)

* 10:00-10:10: interval for laptop PC connection.(1E2-08, 1E2-09, 1E2-10, 1E2-11, 1E2-12)

1E2-08
Stereoselective synthesis of axially chiral biphenyls containing a stereogenic tertiary alcohol center in the lactone bridge (Sch. Pharm., TUPLS) º MAEDA, Takuya; YUYAMA, Daisuke; YAMAGUCHI, Satoru; YANAI, Hikaru; SUZUKI, Keisuke; MATSUMOTO, Takashi

1E2-09
Atrop-diastereoselective desymmetrization of biphenyl-2,6-diol derivatives via the formation of medium-ring lactone bridge (Sch. Pharm., TUPLS) º YUYAMA, Daisuke; MAEDA, Takuya; SUGIYAMA, Nanami; YAMAGUCHI, Satoru; YANAI, Hikaru; SUZUKI, Keisuke; MATSUMOTO, Takashi

1E2-10
Stereoselective synthesis of tetrahydrofurans by oxidative cyclization of 1,5-dienes with hydrogen peroxide catalyzed by an Os(III) complex (Grad. Sch. Eng., Osaka Univ.) º SUGIMOTO, Hideki; KANETAKE, Takayuki; ITOH, Shinobu

1E2-11
Synthesis of oxabicyclo compounds by isomerization of cyclic epoxy alcohols (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.; Fac. Sci., Hokkaido Univ.) º IWAKURA, Masaru; TOKURA, Hiroshi; TANINO, Keiji

1E2-12
Bronsted Base-Catalyzed Formal [3+2] Cycloaddition of β,γ-Epoxy Esters with Imines (Grad. Sch. Sci., Tohoku Univ.) º ODAIRA, Kenta; KONDOH, Azusa; TERADA, Masahiro

Chair: IGAWA, Kazunobu (11:10-12:00)

* 11:00-11:10: interval for laptop PC connection.(1E2-14, 1E2-15, 1E2-17, 1E2-18)

1E2-14
Construction of spirocyclic skeleton by intramolecular redox cyclization / Friedel-Crafts reaction sequence (Fac. Sci., Gakushuin Univ.) º KITAMURA, Eriko; MORI, Keiji; AKIYAMA, Takahiko

1E2-15^*
Enantioselective Palladium(0)-Catalyzed Nazarov-type Cyclization (Univ. of Hawaii Department of Chemistry) º KITAMURA, Kei; SHIMADA, Naoyuki; STEWART, Craig; TIUS, Marcus A

1E2-17
Development of Intramolecular Friedel-Crafts Reaction using Dioxinone Derivative (Grad. Sch. Sci., Eng., Tokyo Tech) º AOKI, Yoshifumi; OHMORI, Ken; SUZUKI, Keisuke

1E2-18
Thiol-mediated synthesis of bicyclo-skeleton (Grad. Sch. Sci., Eng., Tokyo Tech) º FUKAZAWA, Takumi; ANDO, Yoshio; OHMORI, Ken; SUZUKI, Keisuke

Thursday, March 26, PM

Chair: SHIGETA, Masayuki (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(1E2-28, 1E2-29, 1E2-30, 1E2-32, 1E2-33)

1E2-28
Enantioselective Cyanosilylation of Ketones Catalyzed by Chiral Lithium(I) Phosphoryl Phenoxides (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º YAMAKAWA, Katsuya; HATANO, Manabu; ISHIHARA, Kazuaki

1E2-29
Enantio-, Regio-, and Substrate-Selective Diels-Alder Reaction Induced by Chiral Cavity of Supramolecular Lewis Acid Catalysts (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º SAKAMOTO, Tatsuhiro; HATANO, Manabu; ISHIHARA, Kazuaki

1E2-30^*
Development of asymmetric 1,3-dipolar cyclization reactions using novel LASC-SWNT catalysts (Grad. Sch. Sci., The Univ. of Tokyo) º XU, Pengyu; KITANOSONO, Taku; KOBAYASHI, Shu

1E2-32
Asymmetric Mukaiyama aldol reactions using novel LASC-SWNT catalysts in water (Grad. Sch. Sci., The Univ. of Tokyo) º MURATA, Naohiro; XU, Pengyu; ZHU, Lei; KITANOSONO, Taku; KOBAYASHI, Shu

1E2-33
Tandem Oxazolidinone Synthesis using Silver Catalyst as π-Lewis acid (Grad. Sch. Sci. Tech., Keio Univ.) º MAWATARI, Takanori; SEKINE, Kohei; YAMADA, Tohru

Chair: OHMORI, Ken (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(1E2-35, 1E2-37, 1E2-38, 1E2-39, 1E2-40)

1E2-35^*
Development of catalytic construction of hydrogen isotope chirality in deuterium oxide (Grad. Sch. Sci., The Univ. of Tokyo) º KITANOSONO, Taku; KOBAYASHI, Shu

1E2-37
Chiral copper catalysis for enantioselective silyl conjugate additions in water (Grad. Sch. Sci., The Univ. of Tokyo) KOBAYASHI, Shu; º LIU, Chang; ZHU, Lei; XU, Pengyu; UENO, Masaharu

1E2-38
Lewis Acid-mediated chiral transfer ring-expansion of Methyl 1-(arylcarbonyl)-2-aryl- cyclopropanecarboxylates to afford dihydronaphthols (Fac. Textile Sci. Technol., Shinshu Univ.) º YAMADA, Kenta; NISHII, Yosinori

1E2-39
Lewis Acid-mediated chiral transfer homo-Michael addition to arylcyclopropanedicarboxyllic dieaster (Fac. Textile Sci. Technol., Shinshu Univ.) º IWATA, Kiitsu; TAKADA, Seijiro; NISHII, Yoshinori

1E2-40
Carbon Dioxide Incorporation Reaction into Allylsilane Compounds based on Alkyne Activation by Silver Catalysts (Fac. Sci. Tech., Keio Univ.) SEKINE, Kohei; º SADAMITSU, Yuta; YAMADA, Tohru

Chair: HACHIYA, Iwao (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(1E2-42, 1E2-43, 1E2-44, 1E2-45, 1E2-46)

1E2-42
Expeditious Construction of Fused Pyran Skeleton by Domino Internal Redox Process (Fac. Sci., Gakushuin Univ.) º UMEHARA, Nobuaki; MORI, Keiji; AKIYAMA, Takahiko

1E2-43
Asymmetric Synthesis of Fused Piperidine Derivatives by the Domino Internal Redox Process (Fac. Sci., Gakushuin Univ.) º ISOGAI, Ryo; MORI, Keiji; AKIYAMA, Takahiko

1E2-44
Synthesis of esters through a novel spontaneous Meinwald rearrangement reaction (RIKEN Synthetic Organic Chemistry Laboratory; CREST, JST; Tokyo Med. and Dental Univ. Graduate School of Medical and Dental Sciences; RIKEN CSRS) º KAKUMOTO, Daiki; NISHIZAWA, Eri; MORITA, Masaki; HIRAI, Go; SODEOKA, Mikiko

1E2-45
Synthesis of Phenanthrene Derivatives Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Bronsted Base (Grad. Sch. Sci., Tohoku Univ.) º AOKI, Takuma; KONDOH, Azusa; TERADA, Masahiro

1E2-46^*
Bronsted Base-Catalyzed Three Component Reaction Utilizing [1,2]-Phospha-Brook Rearrangement (Grad. Sch. Sci., Tohoku Univ.) º KONDOH, Azusa; TERADA, Masahiro

Chair: YAMANAKA, Masahiro (17:00-18:00)

* 16:50-17:00: interval for laptop PC connection.(1E2-49, 1E2-50, 1E2-51, 1E2-52, 1E2-53, 1E2-54)

1E2-49
Facile Preparation of Dihydrooxazines via the Double Addition of 2-Aminoalkanols to Haloalkynes (Grad. Sch. Biosci. Biotech., Tokyo Tech) YAMAGISHI, Masahito; º SHINOHARA, Yuki; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

1E2-50
One-pot Acetylenic-bond Cleavage via the Double Addition of Diamines to Haloalkynes and Aerial Oxidation (Grad. Sch. Biosci. Biotech., Tokyo Tech) YAMAGISHI, Masahito; º SHINOHARA, Yuki; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

1E2-51
Tandem Umpolung Reaction of α-Imino Allyl Esters Followed by Claisen Rearrangement and a Mechanistic Study (Grad. Sch. Eng., Mie Univ.) º KOBAYASHI, Yoshinari; MIZOTA, Isao; SHIMIZU, Makoto

1E2-52
Tandem N-Alkylation/Stereoselective Claisen Rearrangement of α-Imino Allyl Esters Utilizing Umpolung Reaction (Grad. Sch. Eng., Mie Univ.) º FUKAYA, Toshikazu; MIZOTA, Isao; SHIMIZU, Makoto

1E2-53
Synthesis of α-(cyanoalkyl)-β-hydroxyketones via formal rearrangement reaction of epoxy cyanoalcohols (Hokkaido Univ. Graduate School of Chemical Sciences and Engineering) º DOMON, Daisuke; TANINO, Keiji

1E2-54
Synthetic Study of Matemone Containing an Oxindole Using 1.2-Aza-Brook Rearrangement as a Key Reaction (Grad. Sch. Eng., Mie Univ.) º IMAZATO, Hayao; SHIMIZU, Makoto

Friday, March 27, AM

Chair: OGAWA, Narihito (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(2E2-01, 2E2-02, 2E2-03, 2E2-04, 2E2-05)

2E2-01
Iodine-Catalyzed Decarboxylative Amination of β,γ-Unsaturated Carboxylic Acids with Chloramine Salts (Grad. Sch. Eng., Osaka Univ.) º KOJIMA, Takumi; HISHIKAWA, Yusuke; KIYOKAWA, Kensuke; MINAKATA, Satoshi

2E2-02
Nucleophilic Addition of Carboxylic Amides to Haloalkynes and Its Application (Grad. Sch. Biosci. Biotech., Tokyo Tech) ISHII, Azusa; YAMAGISHI, Masahito; º KOSAKA, Kyohei; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

2E2-03
Synthesis of Tripeptides Using Amino Acid Ionic Liquids (Osaka Prefecture University, Ajinomoto Company, Incorporated Graduate School of Science) FUKUYAMA, Takahide; º KURATSU, Mai; RYU, Ilhyong; FURUKAWA, Shinya; INEYAMA, Takashi

2E2-04
Nucleophilic Addition of Amides Leading to N-acyl-N,O-hemiacetals (Sch. Env. Sci. Eng., KUT) º INOUE, Kanami; ASAHARA, Haruyasu; NISHIWAKI, Nagatoshi

2E2-05^*
Synthesis and Chemical Conversion of Acrylamides Having an Electron-Donating Group at the β-position (Sch. Env. Sci. Eng., KUT) º HIRAI, Sho; ASAHARA, Haruyasu; NISHIWAKI, Nagatoshi

Chair: ASAHARA, Haruyasu (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(2E2-08, 2E2-09, 2E2-10, 2E2-11, 2E2-12)

2E2-08
Regio- and stereoselective iodobromination of internal alkynes for synthesis of (E)-1-bromo-2-iodoalkenes. (Grad. Sch. Sci. Tech., Ryukoku Univ.) º SHIOGAI, Ryo; IDE, Masataka; YAUCHI, Yuta; IWASAWA, Tetsuo

2E2-09
Highly Z-selective synthesis of 1,3-dienes by a new Julia-Kocienski type reagent (Fac. Eng., Gifu Univ.) º ASANO, Hideki; KAWANO, Daiki; SEMII, Yutaka; ANDO, Kaori

2E2-10
Synthesis of isoindoline derivatives for ring expansion of subphthalocyanines. (Grad. Sch. Industrial Tech., Nihon Univ.) º TAKEMOTO, Makoto; YOSHINO, Satoru; KOMORIYA, Tomoe; SAKAMOTO, Keiichi

2E2-11
Enantioselective Synthesis of Silacyclopentenol and its Transformations (IMCE, Kyushu Univ.) YOSHIHIRO, Daisuke; º ABE, Yusuke; IGAWA, Kazunobu; TOMOOKA, Katsuhiko

2E2-12^*
Sulfonylcarbamate as a Versatile and Unique Hydroxy-Protecting Group: Protecting Group Stable under Severe Conditions yet Labile under Mild Conditions (RIKEN Synthetic Cellular Chemistry Lab) º MANABE, Shino; ITO, Yukishige

Chair: IGAWA, Kazunobu (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(2E2-15, 2E2-16, 2E2-17, 2E2-19)

2E2-15
The synthesis of inositol-1-phosphate analogues as an PIP-phosphatase inhibitor. (Grad. Sch. Eng., KIT) º NAKAMURA, Shuya; NAGATA, Yuki; NOMIYA, Hiroki; KITAMURA, Mitsuru; OKAUCHI, Tatsuo

2E2-16
Enantioselective Total Synthesis of Anastrephin (Grad. Sch. Biosci. Biotech., Tokyo Tech) º WADA, Kyohei; OGAWA, Narihito; KOBAYASHI, Yuichi

2E2-17^*
Synthesis and Biological Activity of Arylcyclopropylamines as Selective LSD1 Inhibitors (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; Kyoto Pref. Univ. of Med. Graduate School of Medical Science) º MIYAMURA, Shin; ARAKI, Misaho; OTA, Yosuke; ITOH, Yukihiro; SUZUKI, Takayoshi; YAMAGUCHI, Junichiro; ITAMI, Kenichiro

2E2-19^*
Practical Syntheses of Substituted Sondheimer-Wong Diynes (Fac. of Eng., Okayama Univ. of Sci.) º ORITA, Akihiro; XU, Feng; PENG, Lifen; SHINOHARA, Kenta; NISHIDA, Takanori; OTERA, Junzo

Friday, March 27, PM

Chair: NOKAMI, Toshiki (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(2E2-28, 2E2-29, 2E2-30, 2E2-32, 2E2-33)

2E2-28
Trifluoromethylation of carbonyl compound using novel Trifluoromethyl reagents (Grad. Sch. Sci., Eng., Tokyo Tech) º TOYA, Wataru; NAKAMURA, Yuzo; AIKAWA, Kohsuke; MIKAMI, Koichi

2E2-29
Benzylic C(sp³)-H Trifluoromethylation of 6-Membered Heteroaromatic Compounds using BF₂CF₃ as Lewis Acid and Trifluoromethylation Reagent (Grad. Sch. Pharm., The Univ. of Tokyo) º NAGASE, Masahiro; KUNINOBU, Yoichiro; KANAI, Motomu

2E2-30^*
Synthesis of F-containing compounds by electrophilic- or nucleophilic trifluoromethylation (Grad Sch. Eng., Nagoya Inst. of Tech.) º ARIMORI, Sadayuki; NISHIMINE, Takayuki; TAIRA, Hiromi; SHIBATA, Norio

2E2-32
Development of Trifluoromethylthiolation Reactions Using a Novel ⁺SCF₃ Reagent (Grad Sch. Eng., Nagoya Inst. of Tech.) º TAKADA, Masahiro; ARIMORI, Sadayuki; SHIBATA, Norio

2E2-33
Development of catalytic perfluoroalkylations of aryl halides using stable perfluoroalkylzinc reagents (Grad. Sch. Sci., Eng., Tokyo Tech) º YOKOTA, Yuki; NAKAMURA, Yuzo; AIKAWA, Kohsuke; MIKAMI, Koichi

Chair: YAJIMA, Tomoko (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(2E2-35, 2E2-36, 2E2-37, 2E2-38, 2E2-39)

2E2-35
Effects of ortho-substituents on catalytic aromatic perfluoroalkylation (Grad. Sch. Sci. Tech., Gunma Univ.) º KOMODA, Kazuki; SHIMIZU, Naoto; SERIZAWA, Hiroki; AIKAWA, Kohsuke; MIKAMI, Koichi; AMII, Hideki

2E2-36
novel synthesis of trifluoroacetaldehyde equivalents using catalytic reduction of trifluoroacetic acid derivatives (Fac. Eng., Gifu Univ.) FUNABIKI, Kazumasa; º YANO, Yosuke; KURAMOTO, Shingo; KUBOTA, Yasuhiro; MATSUI, Masaki

2E2-37
Direct Difluoromethylations of α-position of Nitriles (Grad. Sch. Sci., Eng., Tokyo Tech) º MARUYAMA, Kenichi; AIKAWA, Kohsuke; MIKAMI, Koichi

2E2-38
Generation and Reaction of Fluoroalkyl Carbanions by Deprotonation (Grad. Sch. Sci. Tech., Gunma Univ.) º KITAHARA, Taku; SUGIISHI, Tsuyuka; AMII, Hideki

2E2-39^*
Asymmetric alkynylation of fluorinated Morita-Baylis-Hillman adducts (Grad Sch. Eng., Nagoya Inst. of Tech.) º OKUSU, Satoshi; OKAZAKI, Hiroki; TOKUNAGA, Etsuko; SHIBATA, Norio

Chair: SUGIISHI, Tsuyuka (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(2E2-42, 2E2-43, 2E2-44, 2E2-45, 2E2-46, 2E2-47)

2E2-42
Payne rearrangement of 3-CF₃-2,3-epoxy alcohols with a substituent at the 3-position (Fac. Eng., Tokyo Univ. of Agri. and Technol.) YAMAZAKI, Takashi; TAKASUKA, Tomoko; º SHONAKA, Moe

2E2-43
The redox type isomerization of β-trifluoromethylated allylic alcohols (Fac. Eng., Tokyo Univ. of Agri. and Technol.) YAMAZAKI, Takashi; º HAMADA, Yoko; TAKASUKA, Tomoko

2E2-44
Radical addition to fluorinated-α-methylenecarboxylic esters (Grad. Sch. Human. Sci., Ochanomizu Univ.) º KASAHARA, Miku; YAJIMA, Tomoko

2E2-45
Development of chiral Pd-catalyzed enantioselective carbonyl-ene reactions of difluoropyruvates (Grad. Sch. Sci., Eng., Tokyo Tech) º YOSHIDA, Seiya; HONDA, Kazuya; AIKAWA, Kohsuke; MIKAMI, Koichi

2E2-46
Ring-opening allylation of gem-difluorocyclopropane derivatives via radical reaction (Fac. Eng., Tottori Univ.) º MASUHARA, Yoshihiro; NARITA, Kento; NOKAMI, Toshiki; ITOH, Toshiyuki

2E2-47
Synthesis of optically pure fluorine-containing epoxide (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º HASHIZUME, Yuka; KATAGIRI, Toshimasa

Chair: HATA, Takeshi (17:00-18:00)

* 16:50-17:00: interval for laptop PC connection.(2E2-49, 2E2-50, 2E2-51, 2E2-52, 2E2-53, 2E2-54)

2E2-49
Gas evolution using perfluoropolyether and its utilization for some organic synthesis. (Grad. Sch. Sci., Osaka Pref. Univ.) º MATAKE, Ryosuke; NIWA, Yuki; MATSUBARA, Hiroshi

2E2-50
Highly stereoselective synthesis of multi substituted fluorine-containing alkenes based on sequential Heck reaction (KIT) º SAKAGUCHI, Yukiho; KONNO, Tsutomu

2E2-51
Hydrosilylation of fluorine-containing 1,3-diene (KIT) º NISHI, Yuji; NAGAI, Kento; KONNO, Tsutomu

2E2-52
Enantioselective Proparglyic Fluoroalkyation based on C-F bond Activation (Grad Sch. Eng., Nagoya Inst. of Tech.) º FUKUHSI, Kazunobu; TAKAYUKI, Nishimine; TAIRA, Hiromi; TOKUNAGA, Etsuko; SHIBATA, Norio

2E2-53
Synthesis of CH2F-containing epoxide via C-F bond cleavage (Grad Sch. Eng., Nagoya Inst. of Tech.) º TANAKA, Junki; ARIMORI, Sadayuki; TOKUNAGA, Etsuko; SHIBATA, Norio

2E2-54
Transformation of Trifluorotoluene Derivatives by TiCl4-Et3SiH System (Fac. Sci., Gakushuin Univ.) º YAMADA, Takayuki; SAITO, Kodai; AKIYAMA, Takahiko

Chair: MATSUBARA, Hiroshi (18:10-18:40)

* 18:00-18:10: interval for laptop PC connection.(2E2-56, 2E2-58)

2E2-56^*
Catalytic fluoride triggers dehydrative oxazolidinone synthesis from CO₂ (Grad. Sch. Sci., Nagoya Univ.) º TAKADA, Yuki; FOO, Siong Wan; YAMAZAKI, Yusuke; NOYORI, Ryoji; SAITO, Susumu

2E2-58
Synthesis of gem-Ethanopyrrolidines via the Nucleophilic Addition of N-(Cyclopropylmethyl)triflamides to Haloalkynes (Grad. Sch. Biosci. Biotech., Tokyo Tech) OGAWA, Shin; º SAKAGUCHI, Eriko; HATA, Takeshi; URABE, Hirokazu

Saturday, March 28, AM

Chair: AKAGAWA, Kengo (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(3E2-01, 3E2-02, 3E2-03, 3E2-04, 3E2-05, 3E2-06)

3E2-01
Solvent Effects on the First Non-enzymatic Dynamic Kinetic Resolution of Racemic 2-(1H-Pyrrol-1-yl)alkanoic Acids Using MA-BTM Combined System (Fac. Sci., Tokyo Univ. of Sci.) º TOKUMARU, Eri; TENGEIJI, Atsushi; NAKAHARA, Takayoshi; SHIINA, Isamu

3E2-02
Kinetic Resolution of Racemic 2-Hydroxyacetals by the Asymmetric Esterification Using MA-BTM Combined System (Fac. Sci., Tokyo Univ. of Sci.) NAKATA, Kenya; º NAKAHARA, Takayoshi; SAITO, Takahiro; SHIINA, Isamu

3E2-03
Rationalization of the Kinetic Resolution of Racemic 2-Hydroxycarbonyl Compounds Using Asymmetric Esterification (Fac. Sci., Tokyo Univ. of Sci.) SHIINA, Isamu; NAKAHARA, Takayoshi; º ISHIKAWA, Ryo; NAKATA, Kenya

3E2-04
Synthesis and Stereochemical Behavior of Nine-membered Dialkoxysilane having Dynamic Planar Chirality (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) IGAWA, Kazunobu; º KUDO, Yudai; MITOMURA, Shogo; MIYASAKA, Shoji; TOMOOKA, Katsuhiko

3E2-05
Design and Synthesis of Novel N-Arylamides possessing Dynamic Axial Chirality (IMCE, Kyushu Univ.) KASHIWAGI, Takeru; º HIRATSUKA, Yuuya; IGAWA, Kazunobu; TOMOOKA, Katsuhiko

3E2-06
Study on Stereochemical Behavior of 1,3-Ketoamide Enolate (IMCE, Kyushu Univ.) KAWASAKI, Yuuya; º KAMIKUBO, Ryota; IGAWA, Kazunobu; TOMOOKA, Katsuhiko

Chair: IGAWA, Kazunobu (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(3E2-08, 3E2-11, 3E2-12, 3E2-13)

3E2-08 Young Scholar Lectures of CSJ
Development of Novel Kinetic Resolution by Catalytic Asymmetric Dehydration Condensation Reaction (Grad. Sch. Fac. Sci. Eng., Shimane Univ.) º NAKATA, Kenya

3E2-11
Peptide-Catalyzed Kinetic Resolution and Desymmetrization of Planar-Chiral Cylcophanes (IIS, The Univ. of Tokyo) º NISHI, Nobuhiro; AKAGAWA, Kengo; KUDO, Kazuaki

3E2-12
Ruthenium-catalyzed highly selective kinetic resolution of H/D isotope chiral compounds (Kyushu Univ. I2CNER) NISHIOKA, Yota; º NAKAGAWA, Yuta; ITO, Yutarou; UCHIDA, Tatsuya; KATSUKI, Tsutomu

3E2-13
Utilization of aminyl radical formed by the radical reduction of 2-(phenylseleno)ethanesulfonamide (Fac. Sci., Kanagawa Univ.) º IWASAKI, Ryo; KIHARA, Nobuhiro

Chair: HASHIMOTO, Takuya (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(3E2-15, 3E2-16, 3E2-17, 3E2-18, 3E2-19)

3E2-15
Intramolecular formal C-H insertion of photochemically-generated siloxycarbenes (Fac. Sci., Gakushuin Univ.; Grad. Sch. Sci., Eng., Tokyo Tech) º NAKADA, Takuma; ISHII, Shuichi; OHYAMA, Tomoya; ITO, Kazuta; ISHIDA, Kento; IWASAWA, Nobuharu; KUSAMA, Hiroyuki

3E2-16
Oxidative Dual Radical Cyclization of 1,6-Heptadienes with Malonamide Derivatives (Grad. Sch. Sci. Technol., Kumamoto Univ.) º HATANO, Shunsuke; NISHINO, Hiroshi

3E2-17
Ring-opening allylation of Spiro-bis-gem-difluorocyclopropane via radical reaction process (Grad. Sch. Eng., Tottori Univ.) º NARITA, Kento; MASUHARA, Yoshihiro; NOKAMI, Toshiki; ITOH, Toshiyuki

3E2-18
Stereoselective radical addition to α-methylene-β-amino esters containing Ellman’s chiral auxiliary group (Grad. Sch. Human. Sci., Ochanomizu Univ.) º SANO, Anna; YAJIMA, Tomoko

3E2-19^*
Development of Residue-Selective Bioconjugation Targeting Native Proteins Using Organoradicals (Grad. Sch. Pharm., The Univ. of Tokyo) º SEKI, Yohei; ABE, Junpei; TOYOTA, Yosuke; SOHMA, Youhei; OISAKI, Kounosuke; KANAI, Motomu

Saturday, March 28, PM

Chair: OISAKI, Kounosuke (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(3E2-28, 3E2-29, 3E2-30, 3E2-31, 3E2-32)

3E2-28
A Bulky Thiyl Radical Catalyst for [3 + 2] Cyclization of Vinylaziridine and Alkenes (Grad. Sch. Sci., Kyoto Univ.) º TAKINO, Kohei; HASHIMOTO, Takuya; MARUOKA, Keiji

3E2-29
Efficient Photolytic C-H Bond Functionalization of Aliphatic Hydrocarbons with Hypervalent Iodine(III) Reagent (Grad. Sch. Sci., Kyoto Univ.) º INADA, Tsubasa; MOTEKI, Shin; MARUOKA, Keiji

3E2-30
New and Efficient Generation of Trifluoromethyl Radicals Using Highly Electrophilic Hypervalent Iodine(III) Under Metal-Free Conditions (Grad. Sch. Sci., Kyoto Univ.) º KASHIWAGI, Hirotaka; MOTEKI, Shin; MARUOKA, Keiji

3E2-31
Pd-catalyzed oxidative coupling of N-Boc oxindoles (RIKEN; Tokyo Med. and Dental Univ.) º SAWAMURA, Miki; HOJO, Daiki; AKINDELE, Tito; SOHTOME, Yoshihiro; SODEOKA, Mikiko

3E2-32^*
Development of Aerobic Cross-Dehydrogenative Coupling Reactions via Single-electron Transfer and Radical Chain Processes (Grad. Sch. Sci., The Univ. of Tokyo) º YOO, Woo-Jin; KOBAYASHI, Shu

Chair: MATSUBARA, Ryosuke (17:00-17:40)

* 16:50-17:00: interval for laptop PC connection.(3E2-49, 3E2-50, 3E2-51, 3E2-52)

3E2-49
Synthesis of π-Conjugated Molecules with Highly Condensed Systems via [4+2] Cycloaddition of Didehydroisobenzoheterole (Sch. Sci. Tech., Kwansei Gakuin Univ.) º MATSUOKA, Suguru; SUGIMOTO, Ryo; CHUDA, Yu; HAMURA, Toshiyuki

3E2-50
Synthesis of Planar Chiral (1,10)Anthracenophanes and Reactivity and Stereochemical Behavior Thereof (Sch. Sci. Tech., Kwansei Gakuin Univ.) HAMURA, Toshiyuki; º NISHIDA, Ibuki; MATSUOKA, Suguru; OGAWA, Kouhei; IGAWA, Kazunobu; TOMOOKA, Katsuhiko

3E2-51
Titanium Tetraiodide Induced Cyclization of Cyanoketones into Isoquinolines (Grad. Sch. Eng., Mie Univ.) º SAKATA, Keito; YASHIRO, Kai; HACHIYA, Iwao; SHIMIZU, Makoto

3E2-52
EtAlCl₂/Base-mediated dehydrogenative carboxylation of alkenes (Grad. Sch. Eng., Tohoku Univ.) º WATANABE, Kota; TANAKA, Shinya; HATTORI, Tetsutaro