The 95th Annual Meeting of The Chemical Society of Japan

Date: March 26th - 29th, 2015

Venue: Funabashi Campus, College of Science and Technology, Nihon University / School of Pharmacy, Nihon University, Chiba, Japan

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Room D5

Bldg.10 1022


[Physical Organic Chemistry Reaction Mechanism]


Friday, March 27, AM

Chair: KITAGAWA, Toshikazu (10:00-10:50)

* 9:50-10:00: interval for laptop PC connection.(2D5-07, 2D5-09, 2D5-10, 2D5-11)

2D5-07*
Kinetic studies on generation and cycloaddition reaction of ylide intermediates derived from siloxycarbenes and quinolines (Fac. Sci., Gakushuin Univ.; Grad. Sch. Sci., Eng., Tokyo Tech; Grad. Sch. Sci., Hiroshima Univ.) º ISHIDA, Kento; SATO, Junpei; ICHIKAWA, Kenichi; MIZUNO, Takemi; IWASAWA, Nobuharu; ABE, Manabu; KUSAMA, Hiroyuki

2D5-09
Unexpected Formation of a Phenonium Ion-Containing Salt: Isolation and Mechanistic Analysis (Grad. Sch. Eng., Osaka Pref. Univ.; Osaka Pref. Univ. The Research Institute for Molecular Electronic Devices) º KURAMOTO, Yutaro; MATSUI, Yasunori; OHTA, Eisuke; IKEDA, Hiroshi

2D5-10
The effect of aromaticity in excited-state proton transfer reaction (Grad. Sch. Sci., Shizuoka Univ.) º NISHINA, Naoko; SAKAMOTO, Kenkichi; AIHARA, Jun-ichi

2D5-11
Singlet Oxygen Generation from Lithium Ion Encapsulated Fullerene Nanoparticles Produced by Laser Pulse Irradiation (Grad. Sch. Eng., Osaka Univ.; ALCA, JST) º KOHNO, Naoki; OHKUBO, Kei; FUKUZUMI, Shunichi


Chair: OHKUBO, Kei (11:00-11:50)

* 10:50-11:00: interval for laptop PC connection.(2D5-13, 2D5-14, 2D5-15, 2D5-16, 2D5-17)

2D5-13
Neighboring Group Participation of Carbon-Nucleophile in Oxidation by Hypervalent Iodine (Grad. Sch. Mat. Sci., Univ. of Hyogo) º SHIMOGAKI, Mio; FUJITA, Morifumi; SUGIMURA, Takashi

2D5-14
β-Silyl Effect in Electrophilic Aromatic Substitution of 9,9-Dimethyl-9H-9-silafluorene (Grad. Sch. Eng., Mie Univ.) º YAMAMURA, Yuki; OKAZAKI, Takao; KITAGAWA, Toshikazu

2D5-15
The mechanism analysis of diastereoselective Mukaiyama aldol reaction of β-substituted aldehydes (Grad. Sch. Integrated Arts Sci., Kochi Univ.) º NAKATA, Narumi; KANENO, Daisuke

2D5-16
Reactivity and selectivity of the hydroboration of allylic substituted alkenes. (Grad. Sch. Integrated Arts Sci., Kochi Univ.) º TAKAOKA, Kaname; KANENO, Daisuke

2D5-17
The Reaction Mechanism and Solvent Effect in Diastereoselective Hydride Reduction of α-Substituted Propiophenones (Grad. Sch. Integrated Arts Sci., Kochi Univ.) º SAIGO, Hikari; TABEI, Masaru; KANENO, Daisuke


Friday, March 27, PM

Chair: NAKATA, Kazuhide (13:30-14:20)

* 13:20-13:30: interval for laptop PC connection.(2D5-28, 2D5-29, 2D5-31, 2D5-32)

2D5-28
Non-TST behavior of the isomerization reaction rate of dimethylaminobenzene under high pressure : a molecular dynamics study (Ind. Tech. Ctr. Nagasaki) º SHIGEMITSU, Yasuhiro; OHGA, Yasushi

2D5-29*
Theoretical Analysis on the Rearrangement/Fragmentation Reaction of Vinyl Diazonium Ion Derivatives: Dynamic Effect on the Reaction Pathway (Coll. Sci., Rikkyo Univ.) º SATO, Makoto; YAMATAKA, Hiroshi

2D5-31
Theoretical Study of dynamic effects on the domino reaction (Dept. Eng. Edu. Center, Chiba Inst. of Tech.) º ITOH, Shuhei

2D5-32
Analysing of the Reactivity on Oxidative Addition Step in Suzuki Reaction with Ligand Free Solvent (Grad. Sch. Eng., Osaka Univ.) º HIRAKAWA, Teruo; URAMOTO, Yuta


Chair: MAEDA, Satoshi (14:30-15:10)

* 14:20-14:30: interval for laptop PC connection.(2D5-34, 2D5-36)

2D5-34*
Reaction paths of mechanochemical synthesis for dibenzophenazine (Grad. Sch. Eng., Kyoto Univ.; ESICB, Kyoto Univ.; Ecole Nationale Superieure des Mines d'Albi) SATO, Tohru; º HARUTA, Naoki; FILHO MARQUES DE OLIVEIRA, Paulo; CHAMAYOU, Alain; TANAKA, Kazuyoshi; BARON, Michel

2D5-36*
Construction of Quantitative Structure Activity Relationship Models in Catalytic Asymmetric Reactions by Using L1 Regularization Method (ICR, Kyoto Univ.; Grad. Sch. Sci., Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º YAMAGUCHI, Shigeru; NISHIMURA, Takahiro; SATO, Hirofumi


Chair: KANENO, Daisuke (15:20-16:00)

* 15:10-15:20: interval for laptop PC connection.(2D5-39, 2D5-40, 2D5-41, 2D5-42)

2D5-39
Substituent effects on the gas-phase stabilities of phenyl anions (Hosei Univ. SRC; IMCE, Kyushu Univ.) º NAKATA, Kazuhide; FUJIO, Mizue; TSUNO, Yuho

2D5-40
Theoretical study on the autoxidation mechanism of Et3B/O2 system using GRRM/AFIR method (Sch. Sci., Hokkaido Univ.) º SAKA, Chihiro; UEMATSU, Ryohei; MAEDA, Satoshi; TAKETSUGU, Tetsuya

2D5-41
Exploration of Hypervalent Compounds by the GRRM Method (Grad. Sch. Sci., Tohoku Univ.; National Institute of Informatics) º OHNO, Koichi; SATOH, Hiroko; IWAMOTO, Takeaki

2D5-42
Substituent Effect on the Ground State Spin-multiplicity and Molecular Structure in Cyclobutan-1,3-diylidene Dicarbenes. Formation of the Bicyclo[1.1.0]but-1(3)-ene structure (Grad. Sch. Sci., Hiroshima Univ.; IMCE, Kyushu Univ.) º FUJITA, Yoshiki; ABE, Manabu; SUZUKI, Tatsuya; SHIOTA, Yoshihito; YOSHIZAWA, Kazunari


Saturday, March 28, AM

Chair: NAKAMURA, Yasuyuki (10:00-10:40)

* 9:50-10:00: interval for laptop PC connection.(3D5-07, 3D5-09)

3D5-07*
Notable substituent effect on unusual emission from cyclopropane derivatives (Fac. Sci., Hiroshima Univ.) KANAHARA, Kousei; º ABE, Manabu

3D5-09*
“Excited State C-C Bond Cleavage-Emission” of Biphenyl-Substituted Methylencyclopropanes (Grad. Sch. Eng., Osaka Pref. Univ.; The Research Inst. for Molecular Electronic Devices, Osaka Pref. Univ.) º MATSUI, Yasunori; KIDO, Taiki; OHTA, Eisuke; IKEDA, Hiroshi


Chair: USUI, Satoshi (10:50-11:30)

* 10:40-10:50: interval for laptop PC connection.(3D5-12, 3D5-13, 3D5-15)

3D5-12
Generation of 4,4-Dialkoxy-1,2-diazacyclopentane-3,5-diyls and their reactivity (Fac. Sci., Hiroshima Univ.) º YOSHIDOMI, Shohei; ABE, Manabu

3D5-13*
Elucidation of the termination mechanism of radical polymerization of (meth)acrylates (ICR, Kyoto Univ.; CREST, JST) º NAKAMURA, Yasuyuki; YAMAGO, Shigeru

3D5-15
Solvent cage effect in the selectivity of radical-radical reaction (ICR, Kyoto Univ.; CREST, JST) º OGIHARA, Tasuku; NAKAMURA, Yasuyuki; YAMAGO, Shigeru

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