The 100th Annual Meeting of The Chemical Society of Japan

Date: March 22nd - 25th, 2020

Venue: Noda Campus, Tokyo University of Science, Chiba, Japan

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Room H1

Lecture Hall Bldg. K602


[Organic Chemistry -Reaction and Synthesis- Organometallic Compounds]


Sunday, March 22, AM


Pd

Chair: SEMBA, Kazuhiko (09:00-10:10)

* 8:50-9:00: interval for laptop PC connection.(1H1-01, 1H1-02, 1H1-03, 1H1-04, 1H1-05, 1H1-06, 1H1-07)

1H1-01
Palladium-catalyzed oxidative amination of 1,3-dienes (Fac. Chem. Materials and Bioeng., Kansai Univ.) º TABARU, Kazuki; TORII, Kazuyuki; OBORA, Yasushi

1H1-02
α-Alkylation of Nitriles with Alcohols Catalyzed by Ti-Pd alloys (Fac. Chem. Materials and Bioeng., Kansai Univ.) º SAFUMI, Masatoshi; KONDO, Ryota; OBORA, Yasushi

1H1-03
Palladium-Catalyzed Carbothiolation via Trapping of the σ-alkyl palladium Intermediate with RSTIPS (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º HOSOYA, Yosuke; KOBAYASHI, Ikumi; MIZOGUCHI, Kota; NAKADA, Masahisa

1H1-04
Tuning of the Electronic Properties of Buchwald Phosphine Ligand-Like Imidazo[1,5-a]pyridine Carbene Ligands and Application to Catalysis (Fac. Eng., Gifu Univ.) º SHIBTA, Yoshifuru; IKEYAMA, Yoshiki; KAWASE, Tomoyuki; SHIBAHARA, Fumitoshi; MURAI, Toshiaki

1H1-05#
Palladium-Catalyzed Cyclopropanation of Alkenes Using Acylsilanes (Grad. Sch. Eng., Osaka Univ.) º SAKURAI, Shun; TOBISU, Mamoru

1H1-06
Palladium-Catalyzed Diarylation of Two B-H Bonds in Diethylaminoborane. (Grad. Sch. Eng., Osaka Univ.) º SHIMAZUMI, Ryoma; IGARASHI, Takuya; TOBISU, Mamoru

1H1-07#
Palladium-Catalyzed Transfer Hydration of Dinitriles to Diamides (Grad. Sch. Sci., Nagoya Univ.; RCMS, Nagoya Univ.) NARAOKA, Asuka; NOYORI, Ryoji; º NAKA, Hiroshi


Sunday, March 22, PM

Chair: YORIMITSU, Hideki (12:40-13:40)

* 12:30-12:40: interval for laptop PC connection.(1H1-23, 1H1-26)

1H1-23 CSJ Award for Young Chemists#
Catalyst-enabling aromatic functionalization toward synthesis of unexplored functional molecules (WPI-ITbM, Nagoya Univ.) º MURAKAMI, Kei

1H1-26 Young Scholar Lectures of CSJ
Cross-Coupling Reactions Based on Catalytically Generated Organometallic Species (Grad. Sch. Eng., Kyoto Univ.) º SEMBA, Kazuhiko


Chair: NAKA, Hiroshi (13:50-15:00)

* 13:40-13:50: interval for laptop PC connection.(1H1-30, 1H1-31, 1H1-32, 1H1-34, 1H1-35, 1H1-36)

1H1-30
Allylation Reaction of Aldehydes with 4-Substituted 4,4-Diborylbutenes Catalyzed by Palladium (Grad. Sch. Eng., Kyoto Univ.) MIURA, Tomoya; MURAKAMI, Masahiro; º SHIRATORI, Yota

1H1-31
Asymmetric Suzuki-Miyaura Coupling of 1-bromo-2-naphtoates in Water with Water-Soluble Helically Chiral Polymer Ligands (Grad. Sch. Eng., Kyoto Univ.) º KAMIYA, Naoaki; NAGATA, Yuuya; SUGINOME, Michinori

1H1-32*
Structural Analysis of the Polymer-Supported Palladium Catalysts (RIKEN CSRS) º SATO, Takuma; OHNO, Aya; UOZUMI, Yasuhiro; YAMADA, Yoichi

1H1-34
Catalytic Asymmetric Reactions Using Imidazolidine-containing NCN-Pincer Palladium and Nickel Complexes (Grad. Sch. Sci., Chiba Univ.) º ARASEKI, Kensuke; KAKINO, Junki; ARAI, Takayoshi

1H1-35
In-situ crystallization-induced selective monoarylation of dihaloarenes using mechanochemistry (Grad. Sch. Eng., Hokkaido Univ.; WPI-ICReDD, Hokkaido Univ.) º SEO, Tamae; KUBOTA, Koji; ITO, Hajime

1H1-36
Pd-Catalyzed Asymmetric Synthesis of 2,2'-Diamino-1,1'-Biaryls from Azobenzens (Grad. Sch. Eng., Kyoto Univ.) º ASO, Koki; AKAHORI, Tomohiro; OHGI, Akito; FORMICA, Michele; SEMBA, Kazuhiko; NAKAO, Yoshiaki


Ni

Chair: TAKAHASHI, Kohei (15:10-16:20)

* 15:00-15:10: interval for laptop PC connection.(1H1-38, 1H1-39, 1H1-40, 1H1-41, 1H1-42, 1H1-43, 1H1-44)

1H1-38
Light/Nickel-Promoted Dehydrogenative Coupling of Benzylic and Aldehydic C-H Bonds (Grad. Sch. Eng., Kyoto Univ.) º KAWASAKI, Tairin; ISHIDA, Naoki; MURAKAMI, Masahiro

1H1-39
The nickel-catalyzed decarbonylation of acylsilanes (Grad. Sch. Eng., Osaka Univ.) º NAKATANI, Syun; ITO, Yuri; TOBISU, Mamoru

1H1-40
The aryl-halide-dependent chemospecific Buchwald-Hartwig and Suzuki-Miyaura type couplings using nickel iodide catalyst (RIKEN CSRS) º YAMADA, Yoichi M. A.; DHITAL, Raghu N.; SEN, Abhijit; HU, Hao; SATO, Takuma; UOZUMI, Yasuhiro

1H1-41#
Switchable selectivity between Suzuki-Miyaura coupling and Buchwald-Hartwig coupling promoted by an immobilized nickel catalyst (RIKEN CSRS) º SEN, Abhijit; DHITAL, Raghu N.; OHNO, Aya; SATO, Takuma; YAMADA, Yoichi M. A.

1H1-42
Nickel-Catalyzed Selective Alkylation of Ketones via Origomerization of Ethylene (Sch. Eng., Osaka Univ.) º TSURUTA, Takuya; SHIRATAKI, Hiroshi; IWAMOTO, Hiroaki; OGOSHI, Sensuke

1H1-43
Nickel-Catalyzed Regioselective Difluoroallylation of Indoles via C-F Bond Activation of (Trifluoromethyl)alkenes (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º HIGUMA, Tatsuya; WATABE, Yota; IDE, Keisuke; FUJITA, Takeshi; ICHIKAWA, Junji

1H1-44
Nickel-Catalyzed [4 + 2] Cycloaddition of Styrenes with Arynes: Synthesis of Dihydrophenanthrenes (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º KUBO, Teruhiko; FUJITA, Takeshi; ICHIKAWA, Junji


Pd

Chair: KINOSHITA, Hidenori (16:30-17:40)

* 16:20-16:30: interval for laptop PC connection.(1H1-46, 1H1-48, 1H1-49, 1H1-50, 1H1-51)

1H1-46*#
Pd-Catalyzed Allylic Isocyanation with Cyanide as N-Nucleophile (Grad. Sch. Eng., Hokkaido Univ.) º YURINO, Taiga; TANI, Ryutaro; OHKUMA, Takeshi

1H1-48
Pd-catalyzed Synthesis and Transformation of Functionalized Vinylic Isonitriles (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.; Grad. Sch. Eng., Hokkaido Univ.) º HACHIYA, Asuka; YURINO, Taiga; OHKUMA, Takeshi

1H1-49
Pd-catalyzed Isocyanation of Propargylic Alcohol Derivatives (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.; Grad. Sch. Eng., Hokkaido Univ.) º SUZUKI, Keisuke; YURINO, Taiga; OHKUMA, Takeshi

1H1-50
Palladium-Catalyzed Remote Diborylative Cyclization Reactions of Dienes via Chain Walking (Fac. Sci. Tech., Keio Univ.) º KANNO, Shota; KAKIUCHI, Fumitoshi; KOCHI, Takuya

1H1-51*#
Pd-Catalyzed Decarbonylative Alkylation of Acyl Fluorides (Grad. Sch. Nat. Sci. Technol., Okayama Univ.; RIIS, Okayama Univ.) º FU, Liyan; CHEN, Qiang; NISHIHARA, Yasushi


Chair: OGIWARA, Yohei (17:50-18:50)

* 17:40-17:50: interval for laptop PC connection.(1H1-54, 1H1-56, 1H1-57, 1H1-58, 1H1-59)

1H1-54*#
Development of a Novel Synthetic Method for SGLT2 Inhibitors through Fukuyama Coupling Reaction (Grad. Sch. Eng. Sci., Osaka Univ.) º KATO, Daiki; TALODE, Jalindar Bhausaheb; TSURUGI, Hayato; SEKI, Masahiko; MASHIMA, Kazushi

1H1-56#
Cu-Catalyzed Fukuyama Cross-Coupling of Multi-functionalized Thioesters with Organozinc Reagents (Grad. Sch. Eng. Sci., Osaka Univ.; Tokuyama Corp.) º TALODE, Jalindar Bhausaheb; KATO, Daiki; TSURUGI, Hayato; SEKI, Masahiko; MASHIMA, Kazushi

1H1-57#
Palladium catalyzed cross-coupling reactions in mesoionic liquids (Grad. Sch. Eng., Nagoya Inst. of Tech.) º KURABAYASHI, Hideaki; HIRASHITA, Tsunehisa

1H1-58
Synthesis of Fluorenol via Intramolecular C-H Functionalization (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º KURIMOTO, Yuji; MITSUDO, Koichi; SUGA, Seiji

1H1-59
Synthesis and Reactivity of Late Transition Metal Complexes Having a Ru-Metalloligand (Sch. Sci., Tokyo Tech.) º NAKAMURA, Yuta; SAITOU, Narumasa; TAKAYA, Jun; IWASA, Nobuharu


Monday, March 23, AM


Rh

Chair: MASUDA, Yusuke (09:00-10:10)

* 8:50-9:00: interval for laptop PC connection.(2H1-01, 2H1-02, 2H1-03, 2H1-04, 2H1-05, 2H1-06, 2H1-07)

2H1-01#
Rhodium-Catalyzed C(sp2)-H Alkoxycarbonylation of Indoles without External Additives (Fac. Sci., TUS) º LIAO, Yumeng; SUZUKI, Hirotsugu; MATSUDA, Takanori

2H1-02
Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Acenaphthylene Derivatives (Grad. Sch. Sci., Osaka City Univ.) º NOGUCHI, Hikaru; UMEDA, Moeko; NISHIMURA, Takahiro

2H1-03
Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indene Derivatives (Grad. Sch. Sci., Osaka City Univ.) º UMEDA, Moeko; NISHIMURA, Takahiro

2H1-04
Rh-Catalyzed Reaction of α-Carbonyl Sulfoxonium Ylides and Alkenes: Synthesis of Indanones via [4+1] Cycloaddition (Grad. Sch. Eng., Osaka Univ.) º ANDO, Shunsuke; KOMMAGALLA, Yadagiri; CHATANI, Naoto

2H1-05#
Rhodium(III)-Catalyzed Direct C-H Amidation of Aniline Derivatives Using a Pyrimidyl Directing Group (Grad. Sch. Eng., Osaka Univ.) º KHAKE, Shrikant; CHATANI, Naoto

2H1-06#
Rhodium(I)-Catalyzed Reaction of N-(2-(methylthio)phenyl)benzamides with Maleimide. (Grad. Sch. Eng., Osaka Univ.) º SKHIRI, Aymen; CHATANI, Naoto

2H1-07
Construction of Fused Cyclic Compounds by Rhodium-Catalyzed Dehydrogenative Coupling of Aromatic Carboxylic Acids with Internal Alkynes (Grad. Sch. Sci., Osaka City Univ.) º INAI, Yasuhito; SATOH, Testuya; USUKI, Yoshinosuke


Chair: SUZUKI, Hirotsugu (10:20-11:30)

* 10:10-10:20: interval for laptop PC connection.(2H1-09, 2H1-10, 2H1-11, 2H1-12, 2H1-13, 2H1-14, 2H1-15)

2H1-09
Regioselective Preparation of 2-Haloquinoxalines from a Rh Catalyst and 1-Azido-2-[(2,2-dihalovinyl)(Boc)amino]arenes (Sch. Life Sci. Tech., Tokyo Tech.) º HATA, Takeshi; ABE, Teppei; SHIGETA, Masayuki; URABE, Hirokazu

2H1-10
Synthesis of Nitrogen Containing Fused-Tetracyclic Compounds through Rh-Catalyzed Reaction of Carboxylic Acid with Alkynes (Fac. Sci., Osaka Pref. Univ.) º HIRATA, Daiji; FUKUYAMA, Takahide

2H1-11
Synthesis of Triphosphate Derivatives by Rhodium-catalyzed Addition of Pentaphenylcyclopentaphosphine to Alkynes (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º SAWAHATA, Kyosuke; YAMAGUCHI, Masahiko

2H1-12
Rhodium-Catalyzed Addition of Dialkylphosphinyl Groups to Azobenzenes. (Grad. Sch. Pharm. Sci., Tohoku Univ.) TANII, Saori; º ONO, Koki; ARISAWA, Mieko; YAMAGUCHI, Masahiko

2H1-13
Electron-Deficient Cp-Rhodium(III)-Catalyzed Intramolecular Oxyamination of Alkenes with α-Amino Acid Derivatives (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TAKAHASHI, Hiroto; TANAKA, Ken

2H1-14
Rhodium(III)-Catalyzed Oxidative C-H Bond Olefination of O-Phenyl Carbamates (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TANAKA, Jin; TANAKA, Ken

2H1-15
Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers (Grad. Sch. Eng., Kyoto Univ.) º MIURA, Tomoya; NAKAMURO, Takayuki; NAGATA, Yuuya; MORIYAMA, Daisuke; STEWART, G. Scott; MURAKAMI, Masahiro


Monday, March 23, PM

Chair: IWASAKI, Takanori (12:40-13:50)

* 12:30-12:40: interval for laptop PC connection.(2H1-23, 2H1-25, 2H1-26, 2H1-27, 2H1-29)

2H1-23*#
Rhodium-Catalyzed Stitching Polymerization of Alkynylsilylacetylenes and Their Homologues (Grad. Sch. Eng. Sci., Osaka Univ.) º IKEDA, Sho; SHINTANI, Ryo

2H1-25
Catalytic Synthesis of Benzonaphthosilines by [2 + 2 + 2] Cycloaddition (Grad. Sch. Eng. Sci., Osaka Univ.) º MAESATO, Takumi; SHINTANI, Ryo

2H1-26
Efficient Synthesis of Multi-substituted Fluorenes by Using a Rhodium-Catalyzed Stitching Reaction as the Key Step (Grad. Sch. Eng. Sci., Osaka Univ.) º NISHIDA, Masaki; SHINTANI, Ryo

2H1-27*#
Rhodium-catalyzed meta-Selective Carboxylation Reaction of 1,1-Diarylethylenes via Hydrorhodation-Rhodium Migration (Sch. Sci., Tokyo Tech.) º SAITOU, Takanobu; TORIUMI, Naoyuki; IWASAWA, Nobuharu

2H1-29#
Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)-H Borylation (Fac. Sci., Hokkaido Univ.) º REYES, Ronald; SATO, Miyu; IWAI, Tomohiro; SAWAMURA, Masaya


Chair: KOJIMA, Masahiro (14:00-15:10)

* 13:50-14:00: interval for laptop PC connection.(2H1-31, 2H1-32, 2H1-33, 2H1-34, 2H1-35, 2H1-36, 2H1-37)

2H1-31#
trans-Selective Hydroboration of Terminal Alkynes Catalyzed by PSP Pincer Rh Catalyst (Sch. Sci., Tokyo Tech.) º LYU, Yanzong; TORIUMI, Naoyuki; IWASAWA, Nobuharu

2H1-32
Chemoselective Hydrosilylation of Nitriles to Imines Catalyzed by a Rhodium Complex Having a Pincer-Type Gallylene Ligand (Sch. Sci., Tokyo Tech.) º OGAWA, Koki; NAKAYA, Ryota; TAKAYA, Jun; IWASAWA, Nobuharu

2H1-33
Rhodium-Catalyzed Cross-[2+2+2] Cycloaddition of Teraryl-Linked Diynes with Alkynes (Sch. Mater. & Chem. Tech., Tokyo Tech.) º ORIKI, Tomohiro; SUZUKI, Shunsuke; TANAKA, Ken

2H1-34
Enantioselective Synthesis of Π-extended Aza[7]helicenes Possessing Stable Helical Chirality by Rhodium-Catalyzed [2+2+2] Cycloaddition (Sch. Mater. & Chem. Tech., Tokyo Tech.) º HANADA, Kyoichi; TANAKA, Ken

2H1-35
Rhodium-Catalyzed Oxidation of Peptide Thiols (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º FUKUMOTO, Kohei; YAMAGUCHI, Masahiko

2H1-36
Rhodium-Catalyzed Synthesis of Acylsilanes (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º HAYAKWA, Takeru; YAMAGUTI, Masahiko

2H1-37
Synthesis of Cycloalkyl/Steroidal Heteroaryl Sulfides Using Rhodium-Catalyzed Heteroaryl Exchange Reaction (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º NAKAI, Katsuya; SUZUKI, Ren; YAMAGUCHI, Masahiko


Chair: MICHIGAMI, Kenichi (15:20-16:30)

* 15:10-15:20: interval for laptop PC connection.(2H1-39, 2H1-40, 2H1-41, 2H1-43, 2H1-44)

2H1-39
Enantioselective Synthesis of Axially Chiral Styrenes by Rhodium-Catalyzed [2+2+2] cycloaddition (Sch. Mater. & Chem. Tech., Tokyo Tech.) º YOKOSE, Daisuke; KINOSHITA, Suzuka; TANAKA, Ken

2H1-40
Rhodium-Catalyzed Chemo-, Regio-, Diastereo-, and Enantioselective Cross-Cyclotrimerization of Terminal Alkynes, Acetylenecarboxylates, and Enamides (Sch. Mater. & Chem. Tech., Tokyo Tech.) º FUJII, Kohei; MASUTOMI, Koji; SHIBATA, Yu; TANAKA, Ken

2H1-41*#
Enantioselective Synthesis of π-Extended Chiral Triptycenes and PAH-based Chiral Cyclophanes by Asymmetric [2+2+2] Cycloaddition (Sch. Mater. & Chem. Tech., Tokyo Tech.) º AIDA, Yukimasa; SUGIYAMA, Haruki; UEKUSA, Hidehiro; SHIBATA, Yu; TANAKA, Ken

2H1-43
β-Acylalkylation of Allylbenzene Derivatives via Rhodium-Catalyzed C-C Bond Cleavage (Fac. Sci. Tech., Keio Univ.) º ISHIKAWA, Soya; ONODERA, Syunsuke; KOCHI, Takuya; KAKIUCHI, Fumitoshi

2H1-44*#
Rhodium-Catalyzed Carbon-Carbon Bond Formation via Cleavage of Aryl-Alkenyl Bonds (Fac. Sci. Tech., Keio Univ.) º ONODERA, Shunsuke; TOGASHI, Ryo; ISHIKAWA, Soya; KOCHI, Takuya; KAKIUCHI, Fumitoshi


Chair: SATO, Takuma (16:40-17:40)

* 16:30-16:40: interval for laptop PC connection.(2H1-47, 2H1-48, 2H1-49, 2H1-50, 2H1-51, 2H1-52)

2H1-47
Anti-Markovnikov Hydroamination of Aromatic Terminal Alkynes with Primary Amines Catalyzed by Quinolinolato Rhodium Catalyst (Fac. Sci. Tech., Keio Univ.) º MORIMOTO, Yoshihiko; KOCHI, Takuya; KAKIUCHI, Fumitoshi

2H1-48
Rhodium Complex−Catalyzed Reductive Alkylation of 9,10−Phenanthrenequinone with 2−Norbornenes (Grad. Sch. Eng., Kyoto Univ.) º IMAIZUMI, Takuro; KIMURA, Yu; KONDO, Teruyuki

2H1-49
Highly Enantioselective Synthesis of Axially Chiral PAH Compounds via C-C Bond Activation of Biphenylenes and Their Physical Properties (Sch. Advanced Sci. Eng., Waseda Univ.) º SHIOZAWA, Natsumi; TAKANO, Hideaki; IMAI, Yoshitane; KANYIVA, Kyalo Stephen; SHIBATA, Takanori

2H1-50
Rh(I)/Pd(0)-Catalyzed Cyclocarbonylation Reactions of C-Nucleophile-Tethered Haloarenes Using Aldehydes as a Carbonyl Source (Grad. Sch. Mat. Sci., NAIST) MORIMOTO, Tsumoru; º YAMASHITA, Mana; TOMIIE, Ai; KAKIUCHI, Kiyomi

2H1-51
Enantioselective C(sp3)-H functionalization catalyzed by Cp*Rh(III) /chiral carboxylic acid (Grad. Sch. Pharm., Hokkaido Univ.) º KATO, Yoshimi; LIN, Luqing; KOJIMA, Masahiro; YOSHINO, Tatsuhiko; MATSUNAGA, Shigeki

2H1-52
Rhodium-Catalyzed Reaction Using a Borylsilane as a Synthetic Equivalent of Silylene: [2+2+1] Cycloaddition with Ketone as a Two Atom Component (Grad. Sch. Eng., Kyoto Univ.) º TAKAOKA, Yuta; SASAKI, Ikuo; OHMURA, Toshimichi; SUGINOME, Michinori


Tuesday, March 24, AM


Au

Chair: NAGAO, Kazunori (09:00-09:40)

* 8:50-9:00: interval for laptop PC connection.(3H1-01, 3H1-02, 3H1-03, 3H1-04)

3H1-01
Gold(I)-Catalyzed [2 + 3] Cycloaddition of Difluoroallenes with Nitrile Oxides: Synthesis of Fluorine-Substituted Isoxazoline (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º SAKON, Kazuki; FUCHIBE, Kohei; ICHIKAWA, Junji

3H1-02
Gold(I)-catalyzed [2 + 2] Cycloadditon of Difluoroallenes with Styrenes: Synthesis of Difluoromethylenated Cyclobutanes (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º SASAKI, Mizore; SUTO, Kyosuke; FUSHIHARA, Tatsuki; FUCHIBE, Kohei; ICHIKAWA, Junji

3H1-03
Construction of Nitrogen-Containing Seven- and Eight-Membered Rings by Gold(I)-Catalyzed Cycloisomerization (Sch. Advanced Sci. Eng., Waseda Univ.) º TAKAKI, Asahi; ITO, Mamoru; KANYIVA, Stephen Kyalo; SHIBATA, Takanori

3H1-04
Gold-Catalyzed Dual C-C Bond Activation of Biphenylenes Possessing a Pendant Alkyne under Ambient Temperature (Sch. Advanced Sci. Eng., Waseda Univ.) º OKAZAKI, Sari; NISHIBE, Shun; TAKANO, Hideaki; ITO, Takeharu; SHIOZAWA, Natsumi; KANYIVA, Kyalo Stephen; SHIBATA, Takanori


Tuesday, March 24, PM


Ag

Chair: KUBOTA, Koji (12:40-13:20)

* 12:30-12:40: interval for laptop PC connection.(3H1-23, 3H1-24, 3H1-25, 3H1-26)

3H1-23
Stereoselective Synthesis of (Z)-2-Iodoallylamine Derivatives by the Silver-Catalyzed Reaction of N-Alkylpropargylamines with Iodinating Reagents (Grad. Sch. Eng., Osaka Univ.) FUKUMOTO, Yoshiya; º ISHIBASHI, Hisayasu; CHATANI, Naoto

3H1-24
A mechanistic study of Ag-Catalyzed Benzylic Isocyanation (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º TANGE, Yuji; TAIGA, Yurino; TAKESHI, Ohkuma

3H1-25
Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetamides with a Prolinol-Phosphine Chiral Ligand (Fac. Sci., Hokkaido Univ.) º IMAI, Koji; FUJIOKA, Akane; SHIMIZU, Yohei; SAWAMURA, Masaya


Cu

3H1-26#
Cu-catalyzed Asymmetric Allylic Acylation with Acylsilanes under Photoirradiation (Fac. Sci., Hokkaido Univ.) º UEDA, Yusuke; IWAI, Tomohiro; SAWAMURA, Masaya


Chair: YURINO, Taiga (13:30-14:10)

* 13:20-13:30: interval for laptop PC connection.(3H1-28, 3H1-29, 3H1-30, 3H1-31)

3H1-28
Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines (Grad. Sch. Med. Sci., Kanazawa Univ.) º MITSUI, Atsuhisa; NAGAO, Kazunori; OHMIYA, Hirohisa

3H1-29
Copper-Catalyzed Enantioselective Reductive Coupling of Aldehydes and Propargylic Phosphates (Grad. Sch. Med. Sci., Kanazawa Univ.) º KONDO, Yui; NAGAO, Kazunori; OHMIYA, Hirohisa

3H1-30
Copper-Complex-Mediated Reductive Coupling of CO2 and an Aldehyde for the Synthesis of α-Hydroxycarboxylic Acids (Grad. Sch. Eng., The Univ. of Tokyo) º MASADA, Koichiro; KUSUMOTO, Shuhei; NOZAKI, Kyoko

3H1-31
Copper-Catalyzed Asymmetric Reductive Aldol Reaction Using Unprotected Acrylic Acids (Grad. Sch. Sci., TUS) º YONEOKA, Kenji; SUZUKI, Hirotsugu; MATSUDA, Takanori


Chair: ONODERA, Gen (16:00-16:50)

* 15:50-16:00: interval for laptop PC connection.(3H1-43, 3H1-44, 3H1-45, 3H1-46)

3H1-43
Efficient Synthesis of meta-Aminophenol Derivatives by Cu-catalyzed [1,3]-Alkoxy Rearrangement (Grad. Sch. Sci., Tohoku Univ.) º TACHIBANA, Mai; TASHIRO, Hiroki; NAKAMURA, Itaru; TERADA, Masahiro

3H1-44
Copper-catalyzed cross-coupling reaction at secondary alkyl 2-pyridinesulfonates with organolithium reagents (Sch. Sci. Eng., Meiji Univ.) º SATO, Yuta; KOBAYASHI, Yuichi; OGAWA, Narihito

3H1-45#
Enantioconvergent Intramolecular Coupling of α-Aminobenzylboronic Esters Using Copper-Bipyridine-Based Helically Chiral Polymer Catalysts (Grad. Sch. Eng., Kyoto Univ.) º YOSHINAGA, Yukako; YAMAMOTO, Takeshi; SUGINOME, Michinori

3H1-46*
Computational Mechanistic Investigation of Direct Enantioconvergent Borylation Reaction (Grad. Sch. Eng., Hokkaido Univ.; WPI-ICReDD, Hokkaido Univ.) º OZAWA, Yu; IWAMOTO, Hiroaki; TAKENOUCHI, Yuta; IMAMOTO, Tsuneo; ITO, Hajime


Chair: NISHII, Yuji (17:00-17:50)

* 16:50-17:00: interval for laptop PC connection.(3H1-49, 3H1-50, 3H1-51, 3H1-52, 3H1-53)

3H1-49
Dearomative silylation of indoles and pyrroles (Grad. Sch. Eng., Hokkaido Univ.; WPI-ICReDD, Hokkaido Univ.) º TAKAHASHI, Rikuro; HAYAMA, Keiichi; KUBOTA, Koji; ITO, Hajime

3H1-50
Copper(I)-Catalyzed Enantioselective Borylative Dearomatization of Pyrroles (Grad. Sch. Eng., Hokkaido Univ.; WPI-ICReDD, Hokkaido Univ.) º HAYAMA, Keiichi; KOJIMA, Ryoto; KUBOTA, Koji; ITO, Hajime

3H1-51
Study on Synthesis of Oxaborole toward Highly Selective Formation of Tri- and Tetrasubstituted Alkenes (Grad. Sch. Eng., Nagasaki Univ.) º SUEYOSHI, Tatsumi; NUNODA, Akira; AKA, Yuki; FUKUDA, Tsutomu; ONODERA, Gen; KIMURA, Masanari

3H1-52
Synthetic of Organofluorine Compounds Including Tetrafluoroethylene Bridge Structure Adjacent to Heteroatom (Grad. Sch. Eng., Osaka Univ.) º SUNAGAWA, Denise Eimi; ISHIDA, Naoyoshi; IWAMOTO, Hiroaki; OHASHI, Masato; OGOSHI, Sensuke

3H1-53
Synthesis of Imidazo[1,5-a]pyridine Carbene Ligands Bearing Sulfonyl Groups at the 5-Position and Application to Copper-Catalyzed Hydroboration of Alkynes (Fac. Eng., Gifu Univ.) º KANAMORI, Masaya; SHIBAHARA, Fumitoshi; MURAI, Toshiaki


Chair: IWAMOTO, Hiroaki (18:00-18:50)

* 17:50-18:00: interval for laptop PC connection.(3H1-55, 3H1-56, 3H1-57, 3H1-58, 3H1-59)

3H1-55
Degradation of Tetrazole-5-acetamides with a Cu Catalyst and Diaryliodonium Salts (Sch. Life Sci. Tech., Tokyo Tech.) SAGA, Kohei; º ITO, Sho; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

3H1-56
Cu-catalyzed Regioselective Arylation of Tetrazole-5-acetamide's at Their 1-Positions with Diaryliodonium Salts (Sch. Life Sci. Tech., Tokyo Tech.) º SAGA, Kohei; SHIGETA, Masayuki; HATAAKESHI, Takeshi; URABE, Hirokazu

3H1-57
Copper-Mediated C-H Sulfenylation and Selenation of Phenol Derivatives by Phenanthroline-Type Bidentate Auxiliary (Grad. Sch. Eng., Osaka Univ.) º KAJIWARA, Rikuo; TAKAMATSU, Kazutaka; HIRANO, Koji; MIURA, Masahiro

3H1-58
Copper-Catalyzed Regioselective Direct Arylation of Triptycene Derivatives (Grad. Sch. Eng., Osaka Univ.) º UENO, Keisuke; NISHII, Yuji; MIURA, Masahiro

3H1-59
One-Pot Synthesis of alpha-Aminosilanes by Copper-Catalyzed Hydrosilylation/Hydroamination Sequence of Terminal Alkynes (Grad. Sch. Eng., Osaka Univ.) º NISHINO, Soshi; HIRANO, Koji; MIURA, Masahiro


Wednesday, March 25, AM


Ti

Chair: KOCHI, Takuya (09:00-10:10)

* 8:50-9:00: interval for laptop PC connection.(4H1-01, 4H1-02, 4H1-03, 4H1-04, 4H1-05, 4H1-06, 4H1-07)

4H1-01
Cross Coupling Reaction between Alcohols and Alkenyl Halides via C-OH Bond Homolysis (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º TAKAHASHI, Yuki; SUGA, Takuya; UKAJI, Yutaka


Ni

4H1-02
Hydroboration Reaction of Vinylarenes Catalyzed by Nickel Pincer Complexes (Grad. Fac. Eng., Yokohama Natl. Univ.) º SHIOTA, Keisuke; HASHIMOTO, Toru; YAMAGUCHI, Yoshitaka

4H1-03
Nickel-Catalyzed Reductive Zincation of Arylsulfonium Salts (Dep. Chem., Sch. Sci., Kyoto Univ.) º YAMADA, Kodai; YANAGI, Tomoyuki; NOGI, Keisuke; YORIMITSU, Hideki

4H1-04
Nickel-Catalyzed C-F/N-H Annulation of Aromatic Amides with Alkynes via The Cleavage of Carbon-Fluorine Bonds (Grad. Sch. Eng., Osaka Univ.) º NOHIRA, Itsuki; CHATANI, Naoto

4H1-05#
Nickel-Catalyzed C-O/N-H Annulation of Aromatic Amides with Alkynes via the Cleavage of Carbon-Oxygen Bonds (Grad. Sch. Eng., Osaka Univ.) º IYORI, Yasuaki; CHATANI, Naoto

4H1-06
Ni-catalyzed regioselective C-H arylation of arylamines (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º KAWASAKI, Hiroto; AOKI, Yuma; TAKAYA, Hikaru; NAKAMURA, Masaharu

4H1-07
Nickel-Catalyzed Reaction of 2-Butynyl Carbonates with 1,3-Dicarbonyl Compounds (Grad. Sch. Eng., Kyoto Univ.) º KAMINO, Yuka; HORI, Yusaku; ISHIDA, Naoki; MURAKAMI, Masahiro


Wednesday, March 25, PM


Na

Chair: TSURUGI, Hayato (12:40-13:40)

* 12:30-12:40: interval for laptop PC connection.(4H1-23, 4H1-26, 4H1-28)

4H1-23 Young Scholar Lectures of CSJ#
Exploration of Organic Synthesis Using Abundant and Stable Compounds (RIKEN CSRS) º ASAKO, Sobi

4H1-26*#
Preparation of Organosodium Compounds through Halogen-Sodium Exchange (RIKEN CSRS; Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º TAKAHASHI, Ikko; NAKAJIMA, Hirotaka; ILIES, Laurean; ASAKO, Sobi; TAKAI, Kazuhiko


B

4H1-28
Addition of Pyrrole at its β-Position to Electron-Deficient Alkenes (Sch. Sci. Eng., Meiji Univ.) º KAWAKAMI, Maho; SUDO, Takumi; TSUCHIMOTO, Teruhisa


Chair: NAGAO, Kazunori (13:50-14:40)

* 13:40-13:50: interval for laptop PC connection.(4H1-30, 4H1-31, 4H1-33, 4H1-34)

4H1-30
Direct Suzuki-Miyaura Cross-Coupling Reaction of Aryl-B(dan) (Sch. Sci. Eng., Meiji Univ.) º ANDOH, Hiroki; YAJIMA, Tomoki; TANI, Tomohiro; TSUCHIMOTO, Teruhisa

4H1-31*#
Transition-Metal-Free Radical Borylation of Organohalides with Boryl Stannanes (Grad. Sch. Eng., Osaka Univ.) º SUZUKI, Kensuke; NISHIMOTO, Yoshihiro; YASUDA, Makoto

4H1-33
Reductive 1,2-Diboration of Alkynes by Means of Sodium Metal and Trimethoxyborane (Dep. Chem., Sch. Sci., Kyoto Univ.) º ITO, Shiori; FUKAZAWA, Mizuki; TAKAHASHI, Fumiya; NOGI, Keisuke; YORIMITSU, Hideki

4H1-34
Reductive Difunctionalization of Alkenes by Means of Sodium Metal (Dep. Chem., Sch. Sci., Kyoto Univ.) º FUKAZAWA, Mizuki; TAKAHASHI, Fumiya; NOGI, Keisuke; YORIMITSU, Hideki


Chair: NOGI, Keisuke (14:50-15:40)

* 14:40-14:50: interval for laptop PC connection.(4H1-36, 4H1-37, 4H1-38, 4H1-39, 4H1-40)

4H1-36
C(sp3)-C(sp3) Coupling of Tertiary Alkylborates and Secondary Alkyl Halides (Grad. Sch. Med. Sci., Kanazawa Univ.) º TAKEDA, Mitsutaka; NAGAO, Kazunori; OHMIYA, Hirohisa

4H1-37
Tertiary Alkylations of Aldehydes, Ketones or Imines Using Organoboronates and a Base Catalyst (Grad. Sch. Med. Sci., Kanazawa Univ.) º SATO, Yukiya; NAKAMURA, Kei; YABUSHITA, Kenya; NAGAO, Kazunori; OHMIYA, Hirohisa

4H1-38
Direct Visible Light-Excitation of Tertiary Alkylborates Enabling Carbon-Carbon Bond Formation (Grad. Sch. Med. Sci., Kanazawa Univ.; IBB, Tokyo Med. and Dental Univ.; RIKEN BDR) º NAKAMURA, Kei; SATO, Yukiya; SUMIDA, Yuto; HOSOYA, Takamitsu; OHMIYA, Hirohisa

4H1-39#
Synthesis of Ar-B(dan) by the Reaction of Aryl Grignard Reagents with H-B(dan) (Grad. Sch. Eng., Hiroshima Univ.) º LI, Jialun; SEKI, Michinari; OSAKA, Itaru; YOSHIDA, Hiroto

4H1-40
Photo-induced activation of B-B bond: Quadruple Borylation of Terminal Alkynes (Grad. Sch. Pharm., The Univ. of Tokyo) º YUKIMORI, Daiki; NAGASHIMA, Yuki; UCHIYAMA, Masanobu

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